Factors influencing the rearrangement of bis-allylic hydroperoxides by manganese lipoxygenase

Factors influencing the rearrangement of bis-allylic hydroperoxides by manganese lipoxygenase

Manganese lipoxygenase (Mn-LOX) catalyzes the rearrangement of bis-allylic S-hydroperoxides to allylic R-hydroperoxides, but little is known about the reaction mechanism. 1-Linoleoyl-lysoglycerophosphatidylcholine was oxidized in analogy with 18:2n-6 at the bis-allylic carbon with rearrangement to C...

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Bibliographic Details
Main Author: Ernst H. Oliw
Format: Article
Language:English
Published: Elsevier 2008-02-01
Series:Journal of Lipid Research
Subjects:
electron transfer
1-linoleoyl-lysoglycerophosphatidylcholine
mass spectrometry
metalloenzymes
peroxyl radicals
R-lipoxygenase
Online Access:http://www.sciencedirect.com/science/article/pii/S0022227520428639

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http://www.sciencedirect.com/science/article/pii/S0022227520428639

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