Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)

Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)

In the structure of the title compound, [CoCl2(C9H16N2Si)2], the CoII atom is located on an inversion center in a slightly distorted tetrahedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethylsilyl)amino]pyridine ligands. The dihedral angle be...

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Main Authors: Hongbo Tong, Xia Chen, Xiaoyan Xue
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809027937
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spelling doaj-8f359d96b4b74cbc9a2e4737e9c5677c2020-11-25T02:30:16ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658m957m95710.1107/S1600536809027937Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)Hongbo TongXia ChenXiaoyan XueIn the structure of the title compound, [CoCl2(C9H16N2Si)2], the CoII atom is located on an inversion center in a slightly distorted tetrahedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethylsilyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N—H...Cl hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809027937
collection DOAJ
language English
format Article
sources DOAJ
author Hongbo Tong
Xia Chen
Xiaoyan Xue
spellingShingle Hongbo Tong
Xia Chen
Xiaoyan Xue
Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)
Acta Crystallographica Section E
author_facet Hongbo Tong
Xia Chen
Xiaoyan Xue
author_sort Hongbo Tong
title Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)
title_short Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)
title_full Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)
title_fullStr Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)
title_full_unstemmed Dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κN1}cobalt(II)
title_sort dichloridobis{6-methyl-2-[(trimethylsilyl)amino]pyridine-κn1}cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-08-01
description In the structure of the title compound, [CoCl2(C9H16N2Si)2], the CoII atom is located on an inversion center in a slightly distorted tetrahedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethylsilyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N—H...Cl hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809027937
work_keys_str_mv AT hongbotong dichloridobis6methyl2trimethylsilylaminopyridineamp954n1cobaltii
AT xiachen dichloridobis6methyl2trimethylsilylaminopyridineamp954n1cobaltii
AT xiaoyanxue dichloridobis6methyl2trimethylsilylaminopyridineamp954n1cobaltii
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