A purple odyssey: synthesis and structure of 3-amino-4-hydroxy-6-oxocyclohexa-2,4-dien-1-iminium chloride monohydrate
In the cation of the title hydrated molecular salt, C6H7N2O2+·Cl−·H2O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H...Cl, N—H...O, O—H...Cl an...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2016-05-01
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Series: | Acta Crystallographica Section E: Crystallographic Communications |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016005107 |
Summary: | In the cation of the title hydrated molecular salt, C6H7N2O2+·Cl−·H2O, the six-membered ring shows unequal bond lengths consistent with delocalization of electrons over two separate 6π systems with single bonds between them. In the crystal, the components are linked by N—H...Cl, N—H...O, O—H...Cl and O—H...O hydrogen bonds, generating double layers propagating in (100). |
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ISSN: | 2056-9890 |