Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)

Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)

The five-coordinate SnIV atoms in the two crystallographically independent molecules of the title compound, [Sn(C4H9)2(C19H13ClN2O3)], are in distorted cis-C2NO2Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N′-[1-(5-chloro-2-oxidophenyl)e...

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Main Authors: See Mun Lee, Hapipah Mohd Ali, Kong Mun Lo
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810021896
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spelling doaj-914c7d86baa94304a3508398148b9ca42020-11-25T00:54:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m803m80310.1107/S1600536810021896Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)See Mun LeeHapipah Mohd AliKong Mun LoThe five-coordinate SnIV atoms in the two crystallographically independent molecules of the title compound, [Sn(C4H9)2(C19H13ClN2O3)], are in distorted cis-C2NO2Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N′-[1-(5-chloro-2-oxidophenyl)ethylidene]-3-hydroxy-2-naphthohydrazide, displays intermolecular O—H...N hydrogen bonding, which stabilizes the overall compound. http://scripts.iucr.org/cgi-bin/paper?S1600536810021896
collection DOAJ
language English
format Article
sources DOAJ
author See Mun Lee
Hapipah Mohd Ali
Kong Mun Lo
spellingShingle See Mun Lee
Hapipah Mohd Ali
Kong Mun Lo
Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)
Acta Crystallographica Section E
author_facet See Mun Lee
Hapipah Mohd Ali
Kong Mun Lo
author_sort See Mun Lee
title Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)
title_short Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)
title_full Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)
title_fullStr Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)
title_full_unstemmed Dibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O2}tin(IV)
title_sort dibutyl{n′-[1-(5-chloro-2-oxidophenyl-κo)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2n′,o2}tin(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description The five-coordinate SnIV atoms in the two crystallographically independent molecules of the title compound, [Sn(C4H9)2(C19H13ClN2O3)], are in distorted cis-C2NO2Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N′-[1-(5-chloro-2-oxidophenyl)ethylidene]-3-hydroxy-2-naphthohydrazide, displays intermolecular O—H...N hydrogen bonding, which stabilizes the overall compound.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810021896
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AT hapipahmohdali dibutylnamp824215chloro2oxidophenylamp954oethylidene3hydroxy2naphthohydrazidatoamp9542namp8242o2tiniv
AT kongmunlo dibutylnamp824215chloro2oxidophenylamp954oethylidene3hydroxy2naphthohydrazidatoamp9542namp8242o2tiniv
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