trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)
The title compound, [Ni(C17H11ClN)Cl(C3H9P)2], was obtained as a product of the reaction of [Ni(PMe3)4] with a molar equivalent of 2,6-dichloro-N-naphthylbenzaldehydeamine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The NiII a...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-12-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810046234 |
Summary: | The title compound, [Ni(C17H11ClN)Cl(C3H9P)2], was obtained as a product of the reaction of [Ni(PMe3)4] with a molar equivalent of 2,6-dichloro-N-naphthylbenzaldehydeamine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The NiII atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions. |
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ISSN: | 1600-5368 |