trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)

trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)

The title compound, [Ni(C17H11ClN)Cl(C3H9P)2], was obtained as a product of the reaction of [Ni(PMe3)4] with a molar equivalent of 2,6-dichloro-N-naphthylbenzaldehydeamine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The NiII a...

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Main Authors: Ruixia Cao, Hongjian Sun
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810046234
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spelling doaj-91b25df7dcbf497fb91542fd7eab61c62020-11-25T01:33:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1589m158910.1107/S1600536810046234trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)Ruixia CaoHongjian SunThe title compound, [Ni(C17H11ClN)Cl(C3H9P)2], was obtained as a product of the reaction of [Ni(PMe3)4] with a molar equivalent of 2,6-dichloro-N-naphthylbenzaldehydeamine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The NiII atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions. http://scripts.iucr.org/cgi-bin/paper?S1600536810046234
collection DOAJ
language English
format Article
sources DOAJ
author Ruixia Cao
Hongjian Sun
spellingShingle Ruixia Cao
Hongjian Sun
trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)
Acta Crystallographica Section E
author_facet Ruixia Cao
Hongjian Sun
author_sort Ruixia Cao
title trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)
title_short trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)
title_full trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)
title_fullStr trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)
title_full_unstemmed trans-Chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2C1,N}bis(trimethylphosphane)nickel(II)
title_sort trans-chlorido{3-chloro-2-[(1-naphthyl)iminomethyl]phenyl-κ2c1,n}bis(trimethylphosphane)nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description The title compound, [Ni(C17H11ClN)Cl(C3H9P)2], was obtained as a product of the reaction of [Ni(PMe3)4] with a molar equivalent of 2,6-dichloro-N-naphthylbenzaldehydeamine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The NiII atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810046234
work_keys_str_mv AT ruixiacao transchlorido3chloro21naphthyliminomethylphenylamp9542c1nbistrimethylphosphanenickelii
AT hongjiansun transchlorido3chloro21naphthyliminomethylphenylamp9542c1nbistrimethylphosphanenickelii
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