(5-Aminoisophthalato-κN)triaqua(1,10-phenanthroline-κ2N,N′)cobalt(II) trihydrate

(5-Aminoisophthalato-κN)triaqua(1,10-phenanthroline-κ2N,N′)cobalt(II) trihydrate

The CoII atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)3]·3H2O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated CoII atom is chelated by the N-heterocycle. An intermolecular N—H...O hydrogen bond occurs. The carboxylate entity coordinates...

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Bibliographic Details
Main Authors: Kou-Lin Zhang, Guo-Wang Diao, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810040560
Description
Summary:The CoII atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)3]·3H2O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated CoII atom is chelated by the N-heterocycle. An intermolecular N—H...O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O—H...O and N—H...O hydrogen bonds, generating a tightly-held three-dimensional cage-like network.
ISSN:1600-5368

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