Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K

Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K

The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90...

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Main Authors: Alireza Abbasi, Alireza Badiei
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2007-12-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
crystal structure
yttrium
hydrate
bromate
single crystal x-ray diffraction
Online Access:http://www.ijcce.ac.ir/article_7617_b48448dbc32b7c45785bf49804c03364.pdf
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spelling doaj-929c0d6bd06b44fd98863908f36d09412020-11-25T02:53:54ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862007-12-012641231277617Crystal Structure of Nonaaquayttrium(III) Bromate at 100 KAlireza Abbasi0Alireza Badiei1School of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455 Tehran,, I.R. IRANSchool of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455 Tehran,, I.R. IRANThe structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydrated trivalent yttrium(III) ion forms a tricapped trigonal prism, in which the yttrium(III) ion is surrounded by six equidistant water molecules in the prism and three more distant water molecules in capping positions with M-O bond distances of 2.370(2) and 2.446(3) Å, respectively. Relatively strong hydrogen bonds (2.818 and 2.851 Å) from water molecules to the bromate ions stabilize the trigonal prism around the yttrium(III) ions.http://www.ijcce.ac.ir/article_7617_b48448dbc32b7c45785bf49804c03364.pdfcrystal structureyttriumhydratebromatesingle crystal x-ray diffraction
collection DOAJ
language English
format Article
sources DOAJ
author Alireza Abbasi
Alireza Badiei
spellingShingle Alireza Abbasi
Alireza Badiei
Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K
Iranian Journal of Chemistry & Chemical Engineering
crystal structure
yttrium
hydrate
bromate
single crystal x-ray diffraction
author_facet Alireza Abbasi
Alireza Badiei
author_sort Alireza Abbasi
title Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K
title_short Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K
title_full Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K
title_fullStr Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K
title_full_unstemmed Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K
title_sort crystal structure of nonaaquayttrium(iii) bromate at 100 k
publisher Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series Iranian Journal of Chemistry & Chemical Engineering
issn 1021-9986
1021-9986
publishDate 2007-12-01
description The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydrated trivalent yttrium(III) ion forms a tricapped trigonal prism, in which the yttrium(III) ion is surrounded by six equidistant water molecules in the prism and three more distant water molecules in capping positions with M-O bond distances of 2.370(2) and 2.446(3) Å, respectively. Relatively strong hydrogen bonds (2.818 and 2.851 Å) from water molecules to the bromate ions stabilize the trigonal prism around the yttrium(III) ions.
topic crystal structure
yttrium
hydrate
bromate
single crystal x-ray diffraction
url http://www.ijcce.ac.ir/article_7617_b48448dbc32b7c45785bf49804c03364.pdf
work_keys_str_mv AT alirezaabbasi crystalstructureofnonaaquayttriumiiibromateat100k
AT alirezabadiei crystalstructureofnonaaquayttriumiiibromateat100k
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