Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K
The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90...
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2007-12-01
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doaj-929c0d6bd06b44fd98863908f36d09412020-11-25T02:53:54ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862007-12-012641231277617Crystal Structure of Nonaaquayttrium(III) Bromate at 100 KAlireza Abbasi0Alireza Badiei1School of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455 Tehran,, I.R. IRANSchool of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455 Tehran,, I.R. IRANThe structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydrated trivalent yttrium(III) ion forms a tricapped trigonal prism, in which the yttrium(III) ion is surrounded by six equidistant water molecules in the prism and three more distant water molecules in capping positions with M-O bond distances of 2.370(2) and 2.446(3) Å, respectively. Relatively strong hydrogen bonds (2.818 and 2.851 Å) from water molecules to the bromate ions stabilize the trigonal prism around the yttrium(III) ions.http://www.ijcce.ac.ir/article_7617_b48448dbc32b7c45785bf49804c03364.pdfcrystal structureyttriumhydratebromatesingle crystal x-ray diffraction |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Alireza Abbasi Alireza Badiei |
spellingShingle |
Alireza Abbasi Alireza Badiei Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K Iranian Journal of Chemistry & Chemical Engineering crystal structure yttrium hydrate bromate single crystal x-ray diffraction |
author_facet |
Alireza Abbasi Alireza Badiei |
author_sort |
Alireza Abbasi |
title |
Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K |
title_short |
Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K |
title_full |
Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K |
title_fullStr |
Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K |
title_full_unstemmed |
Crystal Structure of Nonaaquayttrium(III) Bromate at 100 K |
title_sort |
crystal structure of nonaaquayttrium(iii) bromate at 100 k |
publisher |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
series |
Iranian Journal of Chemistry & Chemical Engineering |
issn |
1021-9986 1021-9986 |
publishDate |
2007-12-01 |
description |
The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydrated trivalent yttrium(III) ion forms a tricapped trigonal prism, in which the yttrium(III) ion is surrounded by six equidistant water molecules in the prism and three more distant water molecules in capping positions with M-O bond distances of 2.370(2) and 2.446(3) Å, respectively. Relatively strong hydrogen bonds (2.818 and 2.851 Å) from water molecules to the bromate ions stabilize the trigonal prism around the yttrium(III) ions. |
topic |
crystal structure yttrium hydrate bromate single crystal x-ray diffraction |
url |
http://www.ijcce.ac.ir/article_7617_b48448dbc32b7c45785bf49804c03364.pdf |
work_keys_str_mv |
AT alirezaabbasi crystalstructureofnonaaquayttriumiiibromateat100k AT alirezabadiei crystalstructureofnonaaquayttriumiiibromateat100k |
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1724723630762360832 |