Tautomerism in 10-(hydroxyimino)phenanthren-9-one

Tautomerism in 10-(hydroxyimino)phenanthren-9-one

In the title compound, C14H9NO2, a static disorder exists between the keto–oxime and hydroxy–nitroso tautomers, in an approximate ratio of 4.6:1, based on refined occupancies for disordered parts. No intermolecular hydrogen bonding is present in the crystal structure. Ins...

Full description

Bibliographic Details
Main Authors: Dinesh G. Patel, Jason B. Benedict
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681203749X
id doaj-92a71da7a08549cf87cfd6a8ea0333a6
record_format Article
spelling doaj-92a71da7a08549cf87cfd6a8ea0333a62020-11-25T01:37:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810o2871o287110.1107/S160053681203749XTautomerism in 10-(hydroxyimino)phenanthren-9-oneDinesh G. PatelJason B. BenedictIn the title compound, C14H9NO2, a static disorder exists between the keto–oxime and hydroxy–nitroso tautomers, in an approximate ratio of 4.6:1, based on refined occupancies for disordered parts. No intermolecular hydrogen bonding is present in the crystal structure. Instead, both tautomers exhibit similar intramolecular O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S160053681203749X
collection DOAJ
language English
format Article
sources DOAJ
author Dinesh G. Patel
Jason B. Benedict
spellingShingle Dinesh G. Patel
Jason B. Benedict
Tautomerism in 10-(hydroxyimino)phenanthren-9-one
Acta Crystallographica Section E
author_facet Dinesh G. Patel
Jason B. Benedict
author_sort Dinesh G. Patel
title Tautomerism in 10-(hydroxyimino)phenanthren-9-one
title_short Tautomerism in 10-(hydroxyimino)phenanthren-9-one
title_full Tautomerism in 10-(hydroxyimino)phenanthren-9-one
title_fullStr Tautomerism in 10-(hydroxyimino)phenanthren-9-one
title_full_unstemmed Tautomerism in 10-(hydroxyimino)phenanthren-9-one
title_sort tautomerism in 10-(hydroxyimino)phenanthren-9-one
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-10-01
description In the title compound, C14H9NO2, a static disorder exists between the keto–oxime and hydroxy–nitroso tautomers, in an approximate ratio of 4.6:1, based on refined occupancies for disordered parts. No intermolecular hydrogen bonding is present in the crystal structure. Instead, both tautomers exhibit similar intramolecular O—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S160053681203749X
work_keys_str_mv AT dineshgpatel tautomerismin10hydroxyiminophenanthren9one
AT jasonbbenedict tautomerismin10hydroxyiminophenanthren9one
_version_ 1725055957395832832

Similar Items