Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate

Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate

The asymmetric unit of the title compound, [PtCl2(C6H4NO2)2]·CH3CN, contains a neutral PtIV complex and an acetonitrile solvent molecule. In the complex, the Pt4+ atom is six-coordinated in a distorted octahedral environment by two N atoms and two O atoms from two pyridinecarboxylate (p...

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Main Authors: Nam-Ho Kim, In-Chul Hwang, Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2009-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809017966
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spelling doaj-92bbf233bcb64cd3b477c76ae4668a032020-11-25T02:11:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m667m66710.1107/S1600536809017966Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvateNam-Ho KimIn-Chul HwangKwang HaThe asymmetric unit of the title compound, [PtCl2(C6H4NO2)2]·CH3CN, contains a neutral PtIV complex and an acetonitrile solvent molecule. In the complex, the Pt4+ atom is six-coordinated in a distorted octahedral environment by two N atoms and two O atoms from two pyridinecarboxylate (pic) ligands and two Cl atoms. The Cl atoms are cis with respect to each other. The compound displays inter- and intramolecular C—H...O and C—H...Cl hydrogen bonding. http://scripts.iucr.org/cgi-bin/paper?S1600536809017966
collection DOAJ
language English
format Article
sources DOAJ
author Nam-Ho Kim
In-Chul Hwang
Kwang Ha
spellingShingle Nam-Ho Kim
In-Chul Hwang
Kwang Ha
Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate
Acta Crystallographica Section E
author_facet Nam-Ho Kim
In-Chul Hwang
Kwang Ha
author_sort Nam-Ho Kim
title Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate
title_short Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate
title_full Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate
title_fullStr Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate
title_full_unstemmed Dichloridobis(pyridine-2-carboxylato-κ2N,O)platinum(IV) acetonitrile solvate
title_sort dichloridobis(pyridine-2-carboxylato-κ2n,o)platinum(iv) acetonitrile solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-06-01
description The asymmetric unit of the title compound, [PtCl2(C6H4NO2)2]·CH3CN, contains a neutral PtIV complex and an acetonitrile solvent molecule. In the complex, the Pt4+ atom is six-coordinated in a distorted octahedral environment by two N atoms and two O atoms from two pyridinecarboxylate (pic) ligands and two Cl atoms. The Cl atoms are cis with respect to each other. The compound displays inter- and intramolecular C—H...O and C—H...Cl hydrogen bonding.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809017966
work_keys_str_mv AT namhokim dichloridobispyridine2carboxylatoamp9542noplatinumivacetonitrilesolvate
AT inchulhwang dichloridobispyridine2carboxylatoamp9542noplatinumivacetonitrilesolvate
AT kwangha dichloridobispyridine2carboxylatoamp9542noplatinumivacetonitrilesolvate
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