Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate

Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate

The title compound, [Ti(C5H5)2(C16H11NO5)]·H2O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxylate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized a...

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Main Authors: Fanghua Zhu, Yuancheng Qin, Jiehong Lei, Lin Zhang, Qiang Yin
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810021148
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spelling doaj-93a540d3a94246549be3f1f8c8bb45992020-11-25T01:39:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m769m77010.1107/S1600536810021148Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrateFanghua ZhuYuancheng QinJiehong LeiLin ZhangQiang YinThe title compound, [Ti(C5H5)2(C16H11NO5)]·H2O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxylate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water molecule forms strong O—H...O hydrogen bonds with the carboxylate O atoms of the Ti complex, which play an important role in the connection of adjacent molecules. In addition, weak intermolecular C—H...O hydrogen bonds also contribute to the crystal packing arrangement. http://scripts.iucr.org/cgi-bin/paper?S1600536810021148
collection DOAJ
language English
format Article
sources DOAJ
author Fanghua Zhu
Yuancheng Qin
Jiehong Lei
Lin Zhang
Qiang Yin
spellingShingle Fanghua Zhu
Yuancheng Qin
Jiehong Lei
Lin Zhang
Qiang Yin
Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate
Acta Crystallographica Section E
author_facet Fanghua Zhu
Yuancheng Qin
Jiehong Lei
Lin Zhang
Qiang Yin
author_sort Fanghua Zhu
title Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate
title_short Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate
title_full Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate
title_fullStr Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate
title_full_unstemmed Dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(IV) monohydrate
title_sort dicylopentadienyl[4-(4-vinylbenzyloxy)pyridine-2,6-dicarboxylato]titanium(iv) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description The title compound, [Ti(C5H5)2(C16H11NO5)]·H2O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxylate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water molecule forms strong O—H...O hydrogen bonds with the carboxylate O atoms of the Ti complex, which play an important role in the connection of adjacent molecules. In addition, weak intermolecular C—H...O hydrogen bonds also contribute to the crystal packing arrangement.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810021148
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AT yuanchengqin dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
AT jiehonglei dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
AT linzhang dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
AT qiangyin dicylopentadienyl44vinylbenzyloxypyridine26dicarboxylatotitaniumivmonohydrate
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