Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate

Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate

In the title centrosymmetric binuclear CdII compound, [Cd2(C7H5O3)4(C6H6N2O)2]·4H2O, the six-coordinated CdII atom is chelated by the carboxylate groups of the two 3-hydroxybenzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. I...

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Main Authors: Ibrahim Göker Zaman, Nagihan Çaylak Delibaş, Hacali Necefoğlu, Tuncer Hökelek
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681200219X
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spelling doaj-940a027fa1804e32a12ef6c5135b24aa2020-11-24T21:28:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m198m19910.1107/S160053681200219XBis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrateIbrahim Göker ZamanNagihan Çaylak DelibaşHacali NecefoğluTuncer HökelekIn the title centrosymmetric binuclear CdII compound, [Cd2(C7H5O3)4(C6H6N2O)2]·4H2O, the six-coordinated CdII atom is chelated by the carboxylate groups of the two 3-hydroxybenzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O—H...O, N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network. π–π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure.http://scripts.iucr.org/cgi-bin/paper?S160053681200219X
collection DOAJ
language English
format Article
sources DOAJ
author Ibrahim Göker Zaman
Nagihan Çaylak Delibaş
Hacali Necefoğlu
Tuncer Hökelek
spellingShingle Ibrahim Göker Zaman
Nagihan Çaylak Delibaş
Hacali Necefoğlu
Tuncer Hökelek
Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate
Acta Crystallographica Section E
author_facet Ibrahim Göker Zaman
Nagihan Çaylak Delibaş
Hacali Necefoğlu
Tuncer Hökelek
author_sort Ibrahim Göker Zaman
title Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate
title_short Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate
title_full Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate
title_fullStr Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate
title_full_unstemmed Bis(μ-3-hydroxybenzoato)-κ3O1,O1′:O1;κ3O1:O1,O1′-bis[(3-hydroxybenzoato-κ2O,O′)(isonicotinamide-κN1)cadmium] tetrahydrate
title_sort bis(μ-3-hydroxybenzoato)-κ3o1,o1′:o1;κ3o1:o1,o1′-bis[(3-hydroxybenzoato-κ2o,o′)(isonicotinamide-κn1)cadmium] tetrahydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description In the title centrosymmetric binuclear CdII compound, [Cd2(C7H5O3)4(C6H6N2O)2]·4H2O, the six-coordinated CdII atom is chelated by the carboxylate groups of the two 3-hydroxybenzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O—H...O, N—H...O and C—H...O hydrogen bonds link the molecules into a three-dimensional network. π–π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure.
url http://scripts.iucr.org/cgi-bin/paper?S160053681200219X
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