Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation

Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation

<p>Reactions between [M(L)]<sup>2+</sup> [M= Cu(II), Co(II), Cd(II), Zn(II) and Ni(II)] and [Fe(CN)6]<sup>3-</sup> give rise to cyano-bridged assembled bimetallic complexes. Their structures have been proposed by elemental analyses, IR, UV-VIS and <sup>13</sup&...

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Main Authors: Mohammad Nasir Uddin, Jashmin Akter, Mohammed Abul Manchur
Format: Article
Language:English
Published: Universidade Federal de Mato Grosso do Sul 2014-01-01
Series:Orbital: The Electronic Journal of Chemistry
Subjects:
cyano-bridged bimetallic complex
[m(l)]2+ cations
[fe(cn)6]3- anion
antibacterial studies
Online Access:http://orbital.ufms.br/index.php/Chemistry/article/view/512
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spelling doaj-9482080c0bba4fef9125443d16b5d8c32021-07-07T19:22:35ZengUniversidade Federal de Mato Grosso do SulOrbital: The Electronic Journal of Chemistry1984-64282014-01-015425726310.17807/orbital.v5i4.512230Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial EvaluationMohammad Nasir Uddin0Jashmin Akter1Mohammed Abul Manchur2Department of Chemistry, University of ChittagongDepartment of Chemistry, University of ChittagongDepartment of Chemistry, University of Chittagong<p>Reactions between [M(L)]<sup>2+</sup> [M= Cu(II), Co(II), Cd(II), Zn(II) and Ni(II)] and [Fe(CN)6]<sup>3-</sup> give rise to cyano-bridged assembled bimetallic complexes. Their structures have been proposed by elemental analyses, IR, UV-VIS and <sup>13</sup>C NMR spectra, conductance and magnetic measurements studies. The structure is supposed to consist of zigzag chains formed by an alternate array of the cations and [Fe(CN)<sub>6</sub>]<sup>3-</sup> anion having neutral Ni<sub>3</sub>Fe<sub>2</sub> units. Each hexacyanoferrate(III) ion connects three nickel(II) ions using three cis CN<sup>-</sup> groups and the remaining CN<sup>-</sup> groups are terminal. The bridging cyanide ligands co-ordinate to the metal ion in a trans fashion forming trans-ML(CN)<sub>2</sub> moieties. Antibacterial activity of some of the prepared complexes has also been investigated against three human pathogen bacteria.</p>http://orbital.ufms.br/index.php/Chemistry/article/view/512cyano-bridged bimetallic complex[m(l)]2+ cations[fe(cn)6]3- anionantibacterial studies
collection DOAJ
language English
format Article
sources DOAJ
author Mohammad Nasir Uddin
Jashmin Akter
Mohammed Abul Manchur
spellingShingle Mohammad Nasir Uddin
Jashmin Akter
Mohammed Abul Manchur
Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation
Orbital: The Electronic Journal of Chemistry
cyano-bridged bimetallic complex
[m(l)]2+ cations
[fe(cn)6]3- anion
antibacterial studies
author_facet Mohammad Nasir Uddin
Jashmin Akter
Mohammed Abul Manchur
author_sort Mohammad Nasir Uddin
title Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation
title_short Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation
title_full Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation
title_fullStr Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation
title_full_unstemmed Cyano Bridged Bimetallic Compounds of the Type M2+-NC-Fe3+ (M = Co, Ni, Cu, Zn, Cd) Using the [Fe(CN)6]3- Building Block and their Antibacterial Evaluation
title_sort cyano bridged bimetallic compounds of the type m2+-nc-fe3+ (m = co, ni, cu, zn, cd) using the [fe(cn)6]3- building block and their antibacterial evaluation
publisher Universidade Federal de Mato Grosso do Sul
series Orbital: The Electronic Journal of Chemistry
issn 1984-6428
publishDate 2014-01-01
description <p>Reactions between [M(L)]<sup>2+</sup> [M= Cu(II), Co(II), Cd(II), Zn(II) and Ni(II)] and [Fe(CN)6]<sup>3-</sup> give rise to cyano-bridged assembled bimetallic complexes. Their structures have been proposed by elemental analyses, IR, UV-VIS and <sup>13</sup>C NMR spectra, conductance and magnetic measurements studies. The structure is supposed to consist of zigzag chains formed by an alternate array of the cations and [Fe(CN)<sub>6</sub>]<sup>3-</sup> anion having neutral Ni<sub>3</sub>Fe<sub>2</sub> units. Each hexacyanoferrate(III) ion connects three nickel(II) ions using three cis CN<sup>-</sup> groups and the remaining CN<sup>-</sup> groups are terminal. The bridging cyanide ligands co-ordinate to the metal ion in a trans fashion forming trans-ML(CN)<sub>2</sub> moieties. Antibacterial activity of some of the prepared complexes has also been investigated against three human pathogen bacteria.</p>
topic cyano-bridged bimetallic complex
[m(l)]2+ cations
[fe(cn)6]3- anion
antibacterial studies
url http://orbital.ufms.br/index.php/Chemistry/article/view/512
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AT jashminakter cyanobridgedbimetalliccompoundsofthetypem2ncfe3mconicuzncdusingthefecn63buildingblockandtheirantibacterialevaluation
AT mohammedabulmanchur cyanobridgedbimetalliccompoundsofthetypem2ncfe3mconicuzncdusingthefecn63buildingblockandtheirantibacterialevaluation
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