trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
The title compound, [RuCl(C6H7N)2(C27H35N3)]PF6·C3H6O, was obtained unintentionally as the product of the reaction of 1,1′-methylenebis(4-methylpyridinium) hexafluorisophosphate and RuCl3(tpy*) (tpy* is 4,4′,4′′-tri-tert-butyl-2,2&...
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International Union of Crystallography
2012-03-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812005594 |
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doaj-949c646cac5641e2a628d8c6dda1a08c2020-11-25T01:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m300m30010.1107/S1600536812005594trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvateStephen B. ColbranCarolina Gimbert-SuriñachMohan BhadbhadeChristopher RedfordThe title compound, [RuCl(C6H7N)2(C27H35N3)]PF6·C3H6O, was obtained unintentionally as the product of the reaction of 1,1′-methylenebis(4-methylpyridinium) hexafluorisophosphate and RuCl3(tpy*) (tpy* is 4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine) in the presence of triethylamine and LiCl. The molecular structure of the complex displays an octahedral geometry around the RuII ion and the unit cell contains an acetone solvent molecule and one orientationally disordered PF6− anion (occupancy ratio 0.75:0.25) which is hydrogen bonded to two H atoms of the tpy* ligand of the nearest [RuCl(pic)2(tpy*)]+ cation (pic is 4-methylpyridine). One of the tert-butyl groups of the tpy* ligand is also disordered over two sets of sites in a 0.75:0.25 ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812005594 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Stephen B. Colbran Carolina Gimbert-Suriñach Mohan Bhadbhade Christopher Redford |
spellingShingle |
Stephen B. Colbran Carolina Gimbert-Suriñach Mohan Bhadbhade Christopher Redford trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate Acta Crystallographica Section E |
author_facet |
Stephen B. Colbran Carolina Gimbert-Suriñach Mohan Bhadbhade Christopher Redford |
author_sort |
Stephen B. Colbran |
title |
trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate |
title_short |
trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate |
title_full |
trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate |
title_fullStr |
trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate |
title_full_unstemmed |
trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate |
title_sort |
trans-chloridobis(4-methylpyridine-κn)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3n,n′,n′′)ruthenium(ii) hexafluoridophosphate acetone monosolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-03-01 |
description |
The title compound, [RuCl(C6H7N)2(C27H35N3)]PF6·C3H6O, was obtained unintentionally as the product of the reaction of 1,1′-methylenebis(4-methylpyridinium) hexafluorisophosphate and RuCl3(tpy*) (tpy* is 4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine) in the presence of triethylamine and LiCl. The molecular structure of the complex displays an octahedral geometry around the RuII ion and the unit cell contains an acetone solvent molecule and one orientationally disordered PF6− anion (occupancy ratio 0.75:0.25) which is hydrogen bonded to two H atoms of the tpy* ligand of the nearest [RuCl(pic)2(tpy*)]+ cation (pic is 4-methylpyridine). One of the tert-butyl groups of the tpy* ligand is also disordered over two sets of sites in a 0.75:0.25 ratio. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812005594 |
work_keys_str_mv |
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