trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate

The title compound, [RuCl(C6H7N)2(C27H35N3)]PF6·C3H6O, was obtained unintentionally as the product of the reaction of 1,1′-methylenebis(4-methylpyridinium) hexafluorisophosphate and RuCl3(tpy*) (tpy* is 4,4′,4′′-tri-tert-butyl-2,2&...

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Main Authors: Stephen B. Colbran, Carolina Gimbert-Suriñach, Mohan Bhadbhade, Christopher Redford
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812005594
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spelling doaj-949c646cac5641e2a628d8c6dda1a08c2020-11-25T01:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m300m30010.1107/S1600536812005594trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvateStephen B. ColbranCarolina Gimbert-SuriñachMohan BhadbhadeChristopher RedfordThe title compound, [RuCl(C6H7N)2(C27H35N3)]PF6·C3H6O, was obtained unintentionally as the product of the reaction of 1,1′-methylenebis(4-methylpyridinium) hexafluorisophosphate and RuCl3(tpy*) (tpy* is 4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine) in the presence of triethylamine and LiCl. The molecular structure of the complex displays an octahedral geometry around the RuII ion and the unit cell contains an acetone solvent molecule and one orientationally disordered PF6− anion (occupancy ratio 0.75:0.25) which is hydrogen bonded to two H atoms of the tpy* ligand of the nearest [RuCl(pic)2(tpy*)]+ cation (pic is 4-methylpyridine). One of the tert-butyl groups of the tpy* ligand is also disordered over two sets of sites in a 0.75:0.25 ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812005594
collection DOAJ
language English
format Article
sources DOAJ
author Stephen B. Colbran
Carolina Gimbert-Suriñach
Mohan Bhadbhade
Christopher Redford
spellingShingle Stephen B. Colbran
Carolina Gimbert-Suriñach
Mohan Bhadbhade
Christopher Redford
trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
Acta Crystallographica Section E
author_facet Stephen B. Colbran
Carolina Gimbert-Suriñach
Mohan Bhadbhade
Christopher Redford
author_sort Stephen B. Colbran
title trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
title_short trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
title_full trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
title_fullStr trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
title_full_unstemmed trans-Chloridobis(4-methylpyridine-κN)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)ruthenium(II) hexafluoridophosphate acetone monosolvate
title_sort trans-chloridobis(4-methylpyridine-κn)(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine-κ3n,n′,n′′)ruthenium(ii) hexafluoridophosphate acetone monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description The title compound, [RuCl(C6H7N)2(C27H35N3)]PF6·C3H6O, was obtained unintentionally as the product of the reaction of 1,1′-methylenebis(4-methylpyridinium) hexafluorisophosphate and RuCl3(tpy*) (tpy* is 4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine) in the presence of triethylamine and LiCl. The molecular structure of the complex displays an octahedral geometry around the RuII ion and the unit cell contains an acetone solvent molecule and one orientationally disordered PF6− anion (occupancy ratio 0.75:0.25) which is hydrogen bonded to two H atoms of the tpy* ligand of the nearest [RuCl(pic)2(tpy*)]+ cation (pic is 4-methylpyridine). One of the tert-butyl groups of the tpy* ligand is also disordered over two sets of sites in a 0.75:0.25 ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812005594
work_keys_str_mv AT stephenbcolbran transchloridobis4methylpyridineamp954n44amp82424amp8242amp8242tritertbutyl22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242rutheniumiihexafluoridophosphateacetonemonosolvate
AT carolinagimbertsuriamp241ach transchloridobis4methylpyridineamp954n44amp82424amp8242amp8242tritertbutyl22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242rutheniumiihexafluoridophosphateacetonemonosolvate
AT mohanbhadbhade transchloridobis4methylpyridineamp954n44amp82424amp8242amp8242tritertbutyl22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242rutheniumiihexafluoridophosphateacetonemonosolvate
AT christopherredford transchloridobis4methylpyridineamp954n44amp82424amp8242amp8242tritertbutyl22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242rutheniumiihexafluoridophosphateacetonemonosolvate
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