Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate)
Ammonia (NH3) gas is a prominent air pollutant that is frequently found in industrial and livestock production environments. Due to the importance in controlling pollution and protecting public health, the development of new platforms for sensing NH3 at room temperature has attracted great attention...
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doaj-94b7e3ed812640069d5a4e5206044b762020-11-24T21:11:59ZengMDPI AGSensors1424-82202018-04-01184105810.3390/s18041058s18041058Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate)Rafaela S. Andre0Dongwook Kwak1Qiuchen Dong2Wei Zhong3Daniel S. Correa4Luiz H. C. Mattoso5Yu Lei6Department of Chemical and Biomolecular Engineering, University of Connecticut, 191 Auditorium Road, Storrs, CT 06269, USADepartment of Materials Science and Engineering, University of Connecticut, 97 North Eagleville Road, Storrs, CT 06269, USADepartment of Biomedical Engineering, University of Connecticut, 260 Glenbrook Road, Storrs, CT 06269, USADepartment of Chemistry, University of Connecticut, 55 North Eagleville Road, Storrs, CT 06269, USANanotechnology National Laboratory for Agriculture (LNNA), Embrapa Instrumentação, São Carlos 13560-970, SP, BrazilNanotechnology National Laboratory for Agriculture (LNNA), Embrapa Instrumentação, São Carlos 13560-970, SP, BrazilDepartment of Chemical and Biomolecular Engineering, University of Connecticut, 191 Auditorium Road, Storrs, CT 06269, USAAmmonia (NH3) gas is a prominent air pollutant that is frequently found in industrial and livestock production environments. Due to the importance in controlling pollution and protecting public health, the development of new platforms for sensing NH3 at room temperature has attracted great attention. In this study, a sensitive NH3 gas device with enhanced selectivity is developed based on zinc oxide nanofibers (ZnO NFs) decorated with poly(styrene sulfonate) (PSS) and operated at room temperature. ZnO NFs were prepared by electrospinning followed by calcination at 500 °C for 3 h. The electrospun ZnO NFs are characterized to evaluate the properties of the as-prepared sensing materials. The loading of PSS to prepare ZnO NFs/PSS composite is also optimized based on the best sensing performance. Under the optimal composition, ZnO NFs/PSS displays rapid, reversible, and sensitive response upon NH3 exposure at room temperature. The device shows a dynamic linear range up to 100 ppm and a limit of detection of 3.22 ppm and enhanced selectivity toward NH3 in synthetic air, against NO2 and CO, compared to pure ZnO NFs. Additionally, a sensing mechanism is proposed to illustrate the sensing performance using ZnO NFs/PSS composite. Therefore, this study provides a simple methodology to design a sensitive platform for NH3 monitoring at room temperature.http://www.mdpi.com/1424-8220/18/4/1058ZnO NFsPSSNH3 sensorroom temperature sensinggood sensitivity |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Rafaela S. Andre Dongwook Kwak Qiuchen Dong Wei Zhong Daniel S. Correa Luiz H. C. Mattoso Yu Lei |
spellingShingle |
Rafaela S. Andre Dongwook Kwak Qiuchen Dong Wei Zhong Daniel S. Correa Luiz H. C. Mattoso Yu Lei Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate) Sensors ZnO NFs PSS NH3 sensor room temperature sensing good sensitivity |
author_facet |
Rafaela S. Andre Dongwook Kwak Qiuchen Dong Wei Zhong Daniel S. Correa Luiz H. C. Mattoso Yu Lei |
author_sort |
Rafaela S. Andre |
title |
Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate) |
title_short |
Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate) |
title_full |
Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate) |
title_fullStr |
Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate) |
title_full_unstemmed |
Sensitive and Selective NH3 Monitoring at Room Temperature Using ZnO Ceramic Nanofibers Decorated with Poly(styrene sulfonate) |
title_sort |
sensitive and selective nh3 monitoring at room temperature using zno ceramic nanofibers decorated with poly(styrene sulfonate) |
publisher |
MDPI AG |
series |
Sensors |
issn |
1424-8220 |
publishDate |
2018-04-01 |
description |
Ammonia (NH3) gas is a prominent air pollutant that is frequently found in industrial and livestock production environments. Due to the importance in controlling pollution and protecting public health, the development of new platforms for sensing NH3 at room temperature has attracted great attention. In this study, a sensitive NH3 gas device with enhanced selectivity is developed based on zinc oxide nanofibers (ZnO NFs) decorated with poly(styrene sulfonate) (PSS) and operated at room temperature. ZnO NFs were prepared by electrospinning followed by calcination at 500 °C for 3 h. The electrospun ZnO NFs are characterized to evaluate the properties of the as-prepared sensing materials. The loading of PSS to prepare ZnO NFs/PSS composite is also optimized based on the best sensing performance. Under the optimal composition, ZnO NFs/PSS displays rapid, reversible, and sensitive response upon NH3 exposure at room temperature. The device shows a dynamic linear range up to 100 ppm and a limit of detection of 3.22 ppm and enhanced selectivity toward NH3 in synthetic air, against NO2 and CO, compared to pure ZnO NFs. Additionally, a sensing mechanism is proposed to illustrate the sensing performance using ZnO NFs/PSS composite. Therefore, this study provides a simple methodology to design a sensitive platform for NH3 monitoring at room temperature. |
topic |
ZnO NFs PSS NH3 sensor room temperature sensing good sensitivity |
url |
http://www.mdpi.com/1424-8220/18/4/1058 |
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