Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate

Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate

In the title compound, [Co(C7H5O3)(C14H12N2)(H2O)2]NO3·2H2O, the CoII ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxylate O atoms of one 4-hydroxybenzoate anion and two O atoms of two water molecules, in a distorted octahedral environ...

Full description

Bibliographic Details
Main Authors: Peizheng Zhao, Fengmei Yan, Cuiping Zhai
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808038117
id doaj-966ed0198e5a4cda8d46c4d7680714f3
record_format Article
spelling doaj-966ed0198e5a4cda8d46c4d7680714f32020-11-24T21:26:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1591m159210.1107/S1600536808038117Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydratePeizheng ZhaoFengmei YanCuiping ZhaiIn the title compound, [Co(C7H5O3)(C14H12N2)(H2O)2]NO3·2H2O, the CoII ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxylate O atoms of one 4-hydroxybenzoate anion and two O atoms of two water molecules, in a distorted octahedral environment; the two water molecules occupy the apical positions. In the crystal structure, the ionic units and water molecules are linked through O—H...O hydrogen bonds, leading to the formation of a three-dimensional network. In addition, π–π interactions between a pyridine ring of the dmphen ligand and the benzene ring of the hydroxybenzoate anion [centroid–centroid separation = 3.6861 (3) Å] are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536808038117
collection DOAJ
language English
format Article
sources DOAJ
author Peizheng Zhao
Fengmei Yan
Cuiping Zhai
spellingShingle Peizheng Zhao
Fengmei Yan
Cuiping Zhai
Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate
Acta Crystallographica Section E
author_facet Peizheng Zhao
Fengmei Yan
Cuiping Zhai
author_sort Peizheng Zhao
title Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate
title_short Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate
title_full Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate
title_fullStr Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate
title_full_unstemmed Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(4-hydroxybenzoato-κ2O,O′)cobalt(II) nitrate dihydrate
title_sort diaqua(2,9-dimethyl-1,10-phenanthroline-κ2n,n′)(4-hydroxybenzoato-κ2o,o′)cobalt(ii) nitrate dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-12-01
description In the title compound, [Co(C7H5O3)(C14H12N2)(H2O)2]NO3·2H2O, the CoII ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxylate O atoms of one 4-hydroxybenzoate anion and two O atoms of two water molecules, in a distorted octahedral environment; the two water molecules occupy the apical positions. In the crystal structure, the ionic units and water molecules are linked through O—H...O hydrogen bonds, leading to the formation of a three-dimensional network. In addition, π–π interactions between a pyridine ring of the dmphen ligand and the benzene ring of the hydroxybenzoate anion [centroid–centroid separation = 3.6861 (3) Å] are observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808038117
work_keys_str_mv AT peizhengzhao diaqua29dimethyl110phenanthroline9542nn82424hydroxybenzoato9542oo8242cobaltiinitratedihydrate
AT fengmeiyan diaqua29dimethyl110phenanthroline9542nn82424hydroxybenzoato9542oo8242cobaltiinitratedihydrate
AT cuipingzhai diaqua29dimethyl110phenanthroline9542nn82424hydroxybenzoato9542oo8242cobaltiinitratedihydrate
_version_ 1725979859583238144

Similar Items