Pyridine-3-carbonitrile–chloranilic acid–acetonitrile (2/1/2)

In the crystal structure of the title compound, 2C6H4N2·C6H2Cl2O4·2C2H3N, the two symmetry-related pyridine-3-carbonitrile molecules are linked to either side of a chloranilic acid (systematic name: 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) molecule via intermolecular O&...

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Bibliographic Details
Main Authors: Kazuma Gotoh, Hiroyuki Ishida
Format: Article
Language:English
Published: International Union of Crystallography 2009-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809036605
Description
Summary:In the crystal structure of the title compound, 2C6H4N2·C6H2Cl2O4·2C2H3N, the two symmetry-related pyridine-3-carbonitrile molecules are linked to either side of a chloranilic acid (systematic name: 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone) molecule via intermolecular O—H...N hydrogen bonds, giving a centrosymmetric 2:1 unit. The dihedral angle between the pyridine ring and the chloranilic acid plane is 26.71 (6)°. In addition, the two acetonitrile molecules are linked to either side of the 2:1 unit through C—H...N hydrogen bonds, forming a 2:1:2 aggregate. These 2:1:2 aggregates are further linked by weak intermolecular C—H...N and C—H...O hydrogen bonds, forming a tape along the c axis.
ISSN:1600-5368