Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron Residue
A high surface area activated carbon was synthesized by potassium hydroxide (KOH) activation of Finger Citron residue. The pore structure of the as-synthesized activated carbon was characterized by nitrogen adsorption and its carbon dioxide (CO 2 ) sorption capacities at different conditions were me...
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2012-02-01
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Series: | Adsorption Science & Technology |
Online Access: | https://doi.org/10.1260/0263-6174.30.2.183 |
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doaj-97db1f29d0424f9880a9c21e5da92fae2021-04-02T11:45:11ZengHindawi - SAGE PublishingAdsorption Science & Technology0263-61742048-40382012-02-013010.1260/0263-6174.30.2.183Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron ResidueWei Dai0Yuchen Liu1Wei Su2Gengshen Hu3Gang Deng4Xin Hu5 Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, P. R. China Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, P. R. China Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, P. R. China College of Chemistry and Life Sciences, Zhejiang Normal University, Zhejiang Jinhua 321004, P. R. China College of Chemistry and Life Sciences, Zhejiang Normal University, Zhejiang Jinhua 321004, P. R. ChinaA high surface area activated carbon was synthesized by potassium hydroxide (KOH) activation of Finger Citron residue. The pore structure of the as-synthesized activated carbon was characterized by nitrogen adsorption and its carbon dioxide (CO 2 ) sorption capacities at different conditions were measured under high pressure. The BET surface area and total pore volume of the as-synthesized sample were 2887 m 2 /g and 1.23 cm 3 /g, respectively. The dry sample exhibited a CO 2 adsorption capacity of 19.21 mmol/g at 276 K and 3.57 MPa. The CO 2 adsorption uptake increased considerably when an amount of water was pre-adsorbed onto the sample, possibly as a result of the formation of CO 2 hydrate in the pore spaces of the activated carbon. The maximum CO 2 adsorption capacity of the wet sample was found to be 29.02 mmol/g at 273 K and 3.57 MPa. Overall, the results reported confirm that Finger Citron residue could prove a promising precursor for high surface area activated carbon and point to the potential application of activated carbon made from Finger Citron residue in carbon capture and storage.https://doi.org/10.1260/0263-6174.30.2.183 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Wei Dai Yuchen Liu Wei Su Gengshen Hu Gang Deng Xin Hu |
spellingShingle |
Wei Dai Yuchen Liu Wei Su Gengshen Hu Gang Deng Xin Hu Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron Residue Adsorption Science & Technology |
author_facet |
Wei Dai Yuchen Liu Wei Su Gengshen Hu Gang Deng Xin Hu |
author_sort |
Wei Dai |
title |
Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron Residue |
title_short |
Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron Residue |
title_full |
Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron Residue |
title_fullStr |
Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron Residue |
title_full_unstemmed |
Preparation and CO Sorption of a High Surface Area Activated Carbon Obtained from the KOH Activation of Finger Citron Residue |
title_sort |
preparation and co sorption of a high surface area activated carbon obtained from the koh activation of finger citron residue |
publisher |
Hindawi - SAGE Publishing |
series |
Adsorption Science & Technology |
issn |
0263-6174 2048-4038 |
publishDate |
2012-02-01 |
description |
A high surface area activated carbon was synthesized by potassium hydroxide (KOH) activation of Finger Citron residue. The pore structure of the as-synthesized activated carbon was characterized by nitrogen adsorption and its carbon dioxide (CO 2 ) sorption capacities at different conditions were measured under high pressure. The BET surface area and total pore volume of the as-synthesized sample were 2887 m 2 /g and 1.23 cm 3 /g, respectively. The dry sample exhibited a CO 2 adsorption capacity of 19.21 mmol/g at 276 K and 3.57 MPa. The CO 2 adsorption uptake increased considerably when an amount of water was pre-adsorbed onto the sample, possibly as a result of the formation of CO 2 hydrate in the pore spaces of the activated carbon. The maximum CO 2 adsorption capacity of the wet sample was found to be 29.02 mmol/g at 273 K and 3.57 MPa. Overall, the results reported confirm that Finger Citron residue could prove a promising precursor for high surface area activated carbon and point to the potential application of activated carbon made from Finger Citron residue in carbon capture and storage. |
url |
https://doi.org/10.1260/0263-6174.30.2.183 |
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