catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]

catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]

The polymeric title compound, [Cu(C6H2O5)(C12H8N2)(C5H10N2O)]n, is composed of an infinite chain formed along [100] by linking the (1,3-dimethylimidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxylate groups of the furan-2,5-dicarboxylate ligand. The CuII atom, whic...

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Bibliographic Details
Main Authors: Ya-Feng Li, Yue Xu, Xiao-Lin Qin, Yong-Peng Yuan, Wen-Yuan Gao
Format: Article
Language:English
Published: International Union of Crystallography 2012-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681203111X
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spelling doaj-97e108b0ca3645dc8e4da36a464bbece2020-11-25T03:34:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-09-01689m1140m114010.1107/S160053681203111Xcatena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]Ya-Feng LiYue XuXiao-Lin QinYong-Peng YuanWen-Yuan GaoThe polymeric title compound, [Cu(C6H2O5)(C12H8N2)(C5H10N2O)]n, is composed of an infinite chain formed along [100] by linking the (1,3-dimethylimidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxylate groups of the furan-2,5-dicarboxylate ligand. The CuII atom, which lies on a twofold rotation axis, displays a square-pyramidal coordination. The dihedral angles of the 1,10-phenanthroline ligand with respect to the furan rings of the carboxylate anions that are connected to the metal atom are 62.18 (11) and 88.27 (12)°.http://scripts.iucr.org/cgi-bin/paper?S160053681203111X
collection DOAJ
language English
format Article
sources DOAJ
author Ya-Feng Li
Yue Xu
Xiao-Lin Qin
Yong-Peng Yuan
Wen-Yuan Gao
spellingShingle Ya-Feng Li
Yue Xu
Xiao-Lin Qin
Yong-Peng Yuan
Wen-Yuan Gao
catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]
Acta Crystallographica Section E
author_facet Ya-Feng Li
Yue Xu
Xiao-Lin Qin
Yong-Peng Yuan
Wen-Yuan Gao
author_sort Ya-Feng Li
title catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]
title_short catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]
title_full catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]
title_fullStr catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]
title_full_unstemmed catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2O2:O5]
title_sort catena-poly[[(1,3-dimethylimidazolin-2-one-κn)(1,10-phenanthroline-κ2n,n′)copper(ii)]-μ-furan-2,5-dicarboxylato-κ2o2:o5]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-09-01
description The polymeric title compound, [Cu(C6H2O5)(C12H8N2)(C5H10N2O)]n, is composed of an infinite chain formed along [100] by linking the (1,3-dimethylimidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxylate groups of the furan-2,5-dicarboxylate ligand. The CuII atom, which lies on a twofold rotation axis, displays a square-pyramidal coordination. The dihedral angles of the 1,10-phenanthroline ligand with respect to the furan rings of the carboxylate anions that are connected to the metal atom are 62.18 (11) and 88.27 (12)°.
url http://scripts.iucr.org/cgi-bin/paper?S160053681203111X
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AT yuexu catenapoly13dimethylimidazolin2oneamp954n110phenanthrolineamp9542nnamp8242copperiiamp956furan25dicarboxylatoamp9542o2o5
AT xiaolinqin catenapoly13dimethylimidazolin2oneamp954n110phenanthrolineamp9542nnamp8242copperiiamp956furan25dicarboxylatoamp9542o2o5
AT yongpengyuan catenapoly13dimethylimidazolin2oneamp954n110phenanthrolineamp9542nnamp8242copperiiamp956furan25dicarboxylatoamp9542o2o5
AT wenyuangao catenapoly13dimethylimidazolin2oneamp954n110phenanthrolineamp9542nnamp8242copperiiamp956furan25dicarboxylatoamp9542o2o5
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