Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator

Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator

Exceptionally large crystals of posnjakite, Cu4SO4(OH)6(H2O), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to R1 = 0.029 and revealed a structure b...

Full description

Bibliographic Details
Main Authors: Stuart Mills, Jun Aishima, David Aragao, Tom Tudor Caradoc-Davies, Nathan Cowieson, Christine L. Gee, Daniel Ericsson, Stephen Harrop, Santosh Panjikar, Kate Mary Louise Smith, Alan Riboldi-Tunnicliffe, Rachel Williamson, Jason Roy Price
Format: Article
Language:English
Published: International Union of Crystallography 2020-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
copper corrosion
equipment failure
posnjakite
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020008099
id doaj-98564edfb3384f13a1180d2fc949e5bc
record_format Article
spelling doaj-98564edfb3384f13a1180d2fc949e5bc2020-11-25T02:36:54ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-07-017671136113810.1107/S2056989020008099tx2024Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal MonochromatorStuart Mills0Jun Aishima1David Aragao2Tom Tudor Caradoc-Davies3Nathan Cowieson4Christine L. Gee5Daniel Ericsson6Stephen Harrop7Santosh Panjikar8Kate Mary Louise Smith9Alan Riboldi-Tunnicliffe10Rachel Williamson11Jason Roy Price12Geosciences, Museum Victoria, GPO Box 666, Melbourne, Victoria, 3001, AustraliaBrookhaven National Laboratory, 743 Brookhaven Avenue, Upton, NY, USAAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaAustralian Synchrotron, ANSTO - Melbourne, 800 Blackburn Rd, Clayton, VIC, 3168, AustraliaExceptionally large crystals of posnjakite, Cu4SO4(OH)6(H2O), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to R1 = 0.029 and revealed a structure based upon [Cu4(OH)6(H2O)O] sheets, which contain Jahn–Teller-distorted Cu octahedra. The sulfate tetrahedra are bonded to one side of the sheet via corner sharing and linked to successive sheets via extensive hydrogen bonds. The sulfate tetrahedra are split and rotated, which enables additional hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S2056989020008099crystal structurecopper corrosionequipment failureposnjakitehydrogen bonding
collection DOAJ
language English
format Article
sources DOAJ
author Stuart Mills
Jun Aishima
David Aragao
Tom Tudor Caradoc-Davies
Nathan Cowieson
Christine L. Gee
Daniel Ericsson
Stephen Harrop
Santosh Panjikar
Kate Mary Louise Smith
Alan Riboldi-Tunnicliffe
Rachel Williamson
Jason Roy Price
spellingShingle Stuart Mills
Jun Aishima
David Aragao
Tom Tudor Caradoc-Davies
Nathan Cowieson
Christine L. Gee
Daniel Ericsson
Stephen Harrop
Santosh Panjikar
Kate Mary Louise Smith
Alan Riboldi-Tunnicliffe
Rachel Williamson
Jason Roy Price
Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
copper corrosion
equipment failure
posnjakite
hydrogen bonding
author_facet Stuart Mills
Jun Aishima
David Aragao
Tom Tudor Caradoc-Davies
Nathan Cowieson
Christine L. Gee
Daniel Ericsson
Stephen Harrop
Santosh Panjikar
Kate Mary Louise Smith
Alan Riboldi-Tunnicliffe
Rachel Williamson
Jason Roy Price
author_sort Stuart Mills
title Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_short Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_full Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_fullStr Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_full_unstemmed Crystal structure of posnjakite formed in the first crystal water-cooling line of the ANSTO Melbourne Australian Synchrotron MX1 Double Crystal Monochromator
title_sort crystal structure of posnjakite formed in the first crystal water-cooling line of the ansto melbourne australian synchrotron mx1 double crystal monochromator
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2020-07-01
description Exceptionally large crystals of posnjakite, Cu4SO4(OH)6(H2O), formed during corrosion of a Swagelock(tm) Snubber copper gasket within the MX1 beamline at the ANSTO-Melbourne, Australian Synchrotron. The crystal structure was solved using synchrotron radiation to R1 = 0.029 and revealed a structure based upon [Cu4(OH)6(H2O)O] sheets, which contain Jahn–Teller-distorted Cu octahedra. The sulfate tetrahedra are bonded to one side of the sheet via corner sharing and linked to successive sheets via extensive hydrogen bonds. The sulfate tetrahedra are split and rotated, which enables additional hydrogen bonds.
topic crystal structure
copper corrosion
equipment failure
posnjakite
hydrogen bonding
url http://scripts.iucr.org/cgi-bin/paper?S2056989020008099
work_keys_str_mv AT stuartmills crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT junaishima crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT davidaragao crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT tomtudorcaradocdavies crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT nathancowieson crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT christinelgee crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT danielericsson crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT stephenharrop crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT santoshpanjikar crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT katemarylouisesmith crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT alanribolditunnicliffe crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT rachelwilliamson crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
AT jasonroyprice crystalstructureofposnjakiteformedinthefirstcrystalwatercoolinglineoftheanstomelbourneaustraliansynchrotronmx1doublecrystalmonochromator
_version_ 1724798013071687680

Similar Items