OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINES
First, there has been studied the kinetics of low-temperature ozone decomposition by aerosil-immobilized oxyaldimines differing by a nature of a substituent in their benzene ring. In the Hammet equation coordinates, the linear dependence has been found subject to the electron-acceptor properties of...
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Odessa I. I. Mechnikov National University
2015-03-01
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| Series: | Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
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| Online Access: | http://heraldchem.onu.edu.ua/article/view/39902 |
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doaj-985b7b9bce2f4b799f5e9ba52507c9da2020-11-24T20:40:29ZengOdessa I. I. Mechnikov National University Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632015-03-01152152210.18524/2304-0947.2010.2.3990239902OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINEST. L. Rakitskaya0A. S. Truba1A. A. Golub2E. A. Radchenko3Одеський національний університет імені І. І. Мечникова, кафедра неорганічної хімії та хімічної екологіїОдеський національний університет імені І. І. Мечникова, кафедра неорганічної хімії та хімічної екологіїКиївський національний університет імені Тараса Шевченка, кафедра неорганічної хіміїКиївський національний університет імені Тараса Шевченка, кафедра неорганічної хіміїFirst, there has been studied the kinetics of low-temperature ozone decomposition by aerosil-immobilized oxyaldimines differing by a nature of a substituent in their benzene ring. In the Hammet equation coordinates, the linear dependence has been found subject to the electron-acceptor properties of substituents increasing in the sequence: 3-ÎÑÍ3 > Í > 5-Br > 3,5-Cl and the reaction constant ρ has been found to be a negative value, -0,70.http://heraldchem.onu.edu.ua/article/view/39902основи Шиффа, озон, розклад, рівняння Гаммета |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
T. L. Rakitskaya A. S. Truba A. A. Golub E. A. Radchenko |
| spellingShingle |
T. L. Rakitskaya A. S. Truba A. A. Golub E. A. Radchenko OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINES Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ основи Шиффа, озон, розклад, рівняння Гаммета |
| author_facet |
T. L. Rakitskaya A. S. Truba A. A. Golub E. A. Radchenko |
| author_sort |
T. L. Rakitskaya |
| title |
OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINES |
| title_short |
OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINES |
| title_full |
OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINES |
| title_fullStr |
OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINES |
| title_full_unstemmed |
OZONE DECOMPOSITION BY AEROSIL-IMMOBILIZED OXIALDIMINES |
| title_sort |
ozone decomposition by aerosil-immobilized oxialdimines |
| publisher |
Odessa I. I. Mechnikov National University |
| series |
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ |
| issn |
2304-0947 2414-5963 |
| publishDate |
2015-03-01 |
| description |
First, there has been studied the kinetics of low-temperature ozone decomposition
by aerosil-immobilized oxyaldimines differing by a nature of a substituent in their
benzene ring. In the Hammet equation coordinates, the linear dependence has been
found subject to the electron-acceptor properties of substituents increasing in the
sequence: 3-ÎÑÍ3 > Í > 5-Br > 3,5-Cl and the reaction constant ρ has been found to
be a negative value, -0,70. |
| topic |
основи Шиффа, озон, розклад, рівняння Гаммета |
| url |
http://heraldchem.onu.edu.ua/article/view/39902 |
| work_keys_str_mv |
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