Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds

Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds

A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-...

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Main Authors: Rosa M. Gomila, Antoni Frontera, Pere M. DeyÃ, Antoni Costa, Magdalena Capó, Pablo Ballester
Format: Article
Language:English
Published: MDPI AG 2004-04-01
Series:Molecules
Subjects:
Self-assembly
[2]rotaxane
coordinative bond.
Online Access:http://www.mdpi.com/1420-3049/9/5/278/
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spelling doaj-9910a161fe064e1fb61a4ee33bc7bc4d2020-11-24T23:41:43ZengMDPI AGMolecules1420-30492004-04-019527828610.3390/90500278Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate BondsRosa M. GomilaAntoni FronteraPere M. DeyÃAntoni CostaMagdalena CapóPablo BallesterA dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the dynamics of the [2]rotaxane.http://www.mdpi.com/1420-3049/9/5/278/Self-assembly[2]rotaxanecoordinative bond.
collection DOAJ
language English
format Article
sources DOAJ
author Rosa M. Gomila
Antoni Frontera
Pere M. DeyÃ
Antoni Costa
Magdalena Capó
Pablo Ballester
spellingShingle Rosa M. Gomila
Antoni Frontera
Pere M. DeyÃ
Antoni Costa
Magdalena Capó
Pablo Ballester
Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
Molecules
Self-assembly
[2]rotaxane
coordinative bond.
author_facet Rosa M. Gomila
Antoni Frontera
Pere M. DeyÃ
Antoni Costa
Magdalena Capó
Pablo Ballester
author_sort Rosa M. Gomila
title Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
title_short Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
title_full Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
title_fullStr Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
title_full_unstemmed Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
title_sort self-assembly of [2]rotaxane exploiting reversible pt(ii)- pyridine coordinate bonds
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2004-04-01
description A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the dynamics of the [2]rotaxane.
topic Self-assembly
[2]rotaxane
coordinative bond.
url http://www.mdpi.com/1420-3049/9/5/278/
work_keys_str_mv AT rosamgomila selfassemblyof2rotaxaneexploitingreversibleptiipyridinecoordinatebonds
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AT peremdeyaƒ selfassemblyof2rotaxaneexploitingreversibleptiipyridinecoordinatebonds
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