N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation
A novel organic–inorganic hybrid material, namely L-prol-N-pMCM-41, was synthesized via two steps by covalently anchoring N-functionalized proline derivative (L-prol-N-pTMS) into the pore channels of MCM-41 silica. The prepared material was characterized by X-ray diffraction (XRD), thermogravimetric...
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Slovenian Chemical Society
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doaj-9987b7fde6434af38873262493e7697b2020-11-25T01:10:12ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552015-01-016219510210.17344/acsi.2014.755196N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiationKioumars Aghapoor0Mostafa M Amini1Khosrow Jadidi2Hossein Reza Darabi3Shahid Beheshti UniversityShahid Beheshti UniversityShahid Beheshti UniversityChemistry & Chemical Engineering Research Center of IranA novel organic–inorganic hybrid material, namely L-prol-N-pMCM-41, was synthesized via two steps by covalently anchoring N-functionalized proline derivative (L-prol-N-pTMS) into the pore channels of MCM-41 silica. The prepared material was characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), nitrogen adsorption–desorption isotherm, Brunauer–Emmett–Teller (BET) surface area analysis, and Fourier Transform Infrared spectroscopy (FTIR). The immobilized catalyst demonstrated moderate to high catalytic activity and excellent regioselectivity for the ring opening of styrene oxide with aniline derivatives under microwave irradiation and solvent-free conditions. The catalyst could be rapidly separated from the reaction mixture and reused up to five runs with good conversion and high regioselectivity.https://journals.matheo.si/index.php/ACSi/article/view/755Organic-inorganic hybrid materialHeterogeneous catalysisRegioselectivityβ-Amino alcohols |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kioumars Aghapoor Mostafa M Amini Khosrow Jadidi Hossein Reza Darabi |
spellingShingle |
Kioumars Aghapoor Mostafa M Amini Khosrow Jadidi Hossein Reza Darabi N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation Acta Chimica Slovenica Organic-inorganic hybrid material Heterogeneous catalysis Regioselectivity β-Amino alcohols |
author_facet |
Kioumars Aghapoor Mostafa M Amini Khosrow Jadidi Hossein Reza Darabi |
author_sort |
Kioumars Aghapoor |
title |
N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation |
title_short |
N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation |
title_full |
N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation |
title_fullStr |
N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation |
title_full_unstemmed |
N-functionalized L-proline anchored MCM-41: A novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation |
title_sort |
n-functionalized l-proline anchored mcm-41: a novel organic–inorganic hybrid material for solvent-free aminolysis of styrene oxide under microwave irradiation |
publisher |
Slovenian Chemical Society |
series |
Acta Chimica Slovenica |
issn |
1318-0207 1580-3155 |
publishDate |
2015-01-01 |
description |
A novel organic–inorganic hybrid material, namely L-prol-N-pMCM-41, was synthesized via two steps by covalently anchoring N-functionalized proline derivative (L-prol-N-pTMS) into the pore channels of MCM-41 silica. The prepared material was characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), nitrogen adsorption–desorption isotherm, Brunauer–Emmett–Teller (BET) surface area analysis, and Fourier Transform Infrared spectroscopy (FTIR). The immobilized catalyst demonstrated moderate to high catalytic activity and excellent regioselectivity for the ring opening of styrene oxide with aniline derivatives under microwave irradiation and solvent-free conditions. The catalyst could be rapidly separated from the reaction mixture and reused up to five runs with good conversion and high regioselectivity. |
topic |
Organic-inorganic hybrid material Heterogeneous catalysis Regioselectivity β-Amino alcohols |
url |
https://journals.matheo.si/index.php/ACSi/article/view/755 |
work_keys_str_mv |
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