Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics

Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics

The ferroelectric perovskite complex 0.93Na0.5Bi0.5TiO3 – 0.07CaTiO3 (NBT –0.07CT) ceramics were studied by a simple X-ray diffraction upon application of an increasing electric field. It is shown that the field induced rhombohedral (R3c) to monoclinic (Cc) phase transition at room temperature. This...

Full description

Bibliographic Details
Main Authors: Roy Roukos, Nicolas Geoffroy, Denis Chaumont
Format: Article
Language:English
Published: AIP Publishing LLC 2017-01-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4972284
id doaj-9aa3c2b95b514baba96307a16ce90964
record_format Article
spelling doaj-9aa3c2b95b514baba96307a16ce909642020-11-24T21:29:00ZengAIP Publishing LLCAIP Advances2158-32262017-01-0171015030015030-710.1063/1.4972284041612ADVElectric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramicsRoy Roukos0Nicolas Geoffroy1Denis Chaumont2Laboratoire Interdisciplinaire Carnot de Bourgogne UMR 6303 CNRS, Université de Bourgogne, 9 Avenue Alain Savary, 21078 Dijon, FranceLaboratoire Interdisciplinaire Carnot de Bourgogne UMR 6303 CNRS, Université de Bourgogne, 9 Avenue Alain Savary, 21078 Dijon, FranceLaboratoire Interdisciplinaire Carnot de Bourgogne UMR 6303 CNRS, Université de Bourgogne, 9 Avenue Alain Savary, 21078 Dijon, FranceThe ferroelectric perovskite complex 0.93Na0.5Bi0.5TiO3 – 0.07CaTiO3 (NBT –0.07CT) ceramics were studied by a simple X-ray diffraction upon application of an increasing electric field. It is shown that the field induced rhombohedral (R3c) to monoclinic (Cc) phase transition at room temperature. This induced phase is stable after removal the electric field. Our results has been interpreted by intrinsic polarization rotation theory, in comparison with Pb-base system such as PMT-PT, PZN-PT, …near the morphotropic phase boundary (MPB) region. Apparently, the NBT – 0.07CT pretends to have a ferroelectric and structural instability around room temperature.http://dx.doi.org/10.1063/1.4972284
collection DOAJ
language English
format Article
sources DOAJ
author Roy Roukos
Nicolas Geoffroy
Denis Chaumont
spellingShingle Roy Roukos
Nicolas Geoffroy
Denis Chaumont
Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics
AIP Advances
author_facet Roy Roukos
Nicolas Geoffroy
Denis Chaumont
author_sort Roy Roukos
title Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics
title_short Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics
title_full Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics
title_fullStr Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics
title_full_unstemmed Electric field induced monoclinic phase stability in Ca doped Na0.5Bi0.5TiO3: Case of 0.93Na0.5Bi0.5 TiO3 – 0.07CaTiO3 ferroelectric ceramics
title_sort electric field induced monoclinic phase stability in ca doped na0.5bi0.5tio3: case of 0.93na0.5bi0.5 tio3 – 0.07catio3 ferroelectric ceramics
publisher AIP Publishing LLC
series AIP Advances
issn 2158-3226
publishDate 2017-01-01
description The ferroelectric perovskite complex 0.93Na0.5Bi0.5TiO3 – 0.07CaTiO3 (NBT –0.07CT) ceramics were studied by a simple X-ray diffraction upon application of an increasing electric field. It is shown that the field induced rhombohedral (R3c) to monoclinic (Cc) phase transition at room temperature. This induced phase is stable after removal the electric field. Our results has been interpreted by intrinsic polarization rotation theory, in comparison with Pb-base system such as PMT-PT, PZN-PT, …near the morphotropic phase boundary (MPB) region. Apparently, the NBT – 0.07CT pretends to have a ferroelectric and structural instability around room temperature.
url http://dx.doi.org/10.1063/1.4972284
work_keys_str_mv AT royroukos electricfieldinducedmonoclinicphasestabilityincadopedna05bi05tio3caseof093na05bi05tio3007catio3ferroelectricceramics
AT nicolasgeoffroy electricfieldinducedmonoclinicphasestabilityincadopedna05bi05tio3caseof093na05bi05tio3007catio3ferroelectricceramics
AT denischaumont electricfieldinducedmonoclinicphasestabilityincadopedna05bi05tio3caseof093na05bi05tio3007catio3ferroelectricceramics
_version_ 1725967978576478208

Similar Items