1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide
The title compound, C7H15N3OP+·I3−, is a derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The crystal structure is composed of a cage-like 1-methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide cation and a triiodide a...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2008-02-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808001426 |
id |
doaj-9ad70c87a6db417f95cf8c3a55f402f4 |
---|---|
record_format |
Article |
spelling |
doaj-9ad70c87a6db417f95cf8c3a55f402f42020-11-25T02:15:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642o496o49710.1107/S16005368080014261-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodideArmando J. L. PombeiroM. Fátima C. Guedes da SilvaPiotr SmoleńskiAlexander M. KirillovThe title compound, C7H15N3OP+·I3−, is a derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The crystal structure is composed of a cage-like 1-methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide cation and a triiodide anion. The N-methylation of the PTA cage results in a slight elongation of the corresponding C—N bonds, while the oxidation of the P atom leads to a slight shortening of the C—P bonds in comparison with those of PTA. In general, most of the bonding parameters are comparable with those reported for related compounds bearing the PTA core. Two intermolecular C—H...O hydrogen bonds between methylene groups and the P=O group are responsible for the linkage of neighbouring cations into linear one-dimensional hydrogen-bonded chains.http://scripts.iucr.org/cgi-bin/paper?S1600536808001426 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Armando J. L. Pombeiro M. Fátima C. Guedes da Silva Piotr Smoleński Alexander M. Kirillov |
spellingShingle |
Armando J. L. Pombeiro M. Fátima C. Guedes da Silva Piotr Smoleński Alexander M. Kirillov 1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide Acta Crystallographica Section E |
author_facet |
Armando J. L. Pombeiro M. Fátima C. Guedes da Silva Piotr Smoleński Alexander M. Kirillov |
author_sort |
Armando J. L. Pombeiro |
title |
1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide |
title_short |
1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide |
title_full |
1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide |
title_fullStr |
1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide |
title_full_unstemmed |
1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide |
title_sort |
1-methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-02-01 |
description |
The title compound, C7H15N3OP+·I3−, is a derivative of the well known water-soluble aminophosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The crystal structure is composed of a cage-like 1-methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide cation and a triiodide anion. The N-methylation of the PTA cage results in a slight elongation of the corresponding C—N bonds, while the oxidation of the P atom leads to a slight shortening of the C—P bonds in comparison with those of PTA. In general, most of the bonding parameters are comparable with those reported for related compounds bearing the PTA core. Two intermolecular C—H...O hydrogen bonds between methylene groups and the P=O group are responsible for the linkage of neighbouring cations into linear one-dimensional hydrogen-bonded chains. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808001426 |
work_keys_str_mv |
AT armandojlpombeiro 1methyl1azonia35diaza7phosphatricyclo3311decane7oxidetriiodide AT mf225timacguedesdasilva 1methyl1azonia35diaza7phosphatricyclo3311decane7oxidetriiodide AT piotrsmole324ski 1methyl1azonia35diaza7phosphatricyclo3311decane7oxidetriiodide AT alexandermkirillov 1methyl1azonia35diaza7phosphatricyclo3311decane7oxidetriiodide |
_version_ |
1724897963345444864 |