Efficient Synthesis of a Range of Benzosubstituted Macrocyclic Diamides

Some new macrocyclic dibenzotetraoxadiamides, tribenzotetraoxadimides, tribenzopentaoxadiamide, tribenzohexaoxadiamide, and tetrabenzoheptaoxadiamide 15-22 have been prepared. These compounds were obtained in the macrocyclization step by reacting the diamines 6 and 7 with appropriate dicarboxylic ac...

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Main Authors: Hashem Sharghi, Ahmad Reza Massah, Khodabakhsh Niknam
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2000-06-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_10199_3f0816a9e5003cff873ee9a0e8775719.pdf
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spelling doaj-9b154698443a4fc59137707b70cfde482020-11-25T03:31:53ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862000-06-0119161210199Efficient Synthesis of a Range of Benzosubstituted Macrocyclic DiamidesHashem Sharghi0Ahmad Reza Massah1Khodabakhsh Niknam2Department of Chemistry, Shiraz University, Zip code 71454, Shiraz, I.R. IRANDepartment of Chemistry, Shiraz University, Zip code 71454, Shiraz, I.R. IRANDepartment of Chemistry, Shiraz University, Zip code 71454, Shiraz, I.R. IRANSome new macrocyclic dibenzotetraoxadiamides, tribenzotetraoxadimides, tribenzopentaoxadiamide, tribenzohexaoxadiamide, and tetrabenzoheptaoxadiamide 15-22 have been prepared. These compounds were obtained in the macrocyclization step by reacting the diamines 6 and 7 with appropriate dicarboxylic acid dichlorides 8-14. The cyclization does not require high dilution techniques or template effect and provides the expected dilactams in high yields ranging from 63% to 81%.http://www.ijcce.ac.ir/article_10199_3f0816a9e5003cff873ee9a0e8775719.pdfmacrocyclic diamidessynthesisdirect macrocyclizationdicarboxylic acid dichloride
collection DOAJ
language English
format Article
sources DOAJ
author Hashem Sharghi
Ahmad Reza Massah
Khodabakhsh Niknam
spellingShingle Hashem Sharghi
Ahmad Reza Massah
Khodabakhsh Niknam
Efficient Synthesis of a Range of Benzosubstituted Macrocyclic Diamides
Iranian Journal of Chemistry & Chemical Engineering
macrocyclic diamides
synthesis
direct macrocyclization
dicarboxylic acid dichloride
author_facet Hashem Sharghi
Ahmad Reza Massah
Khodabakhsh Niknam
author_sort Hashem Sharghi
title Efficient Synthesis of a Range of Benzosubstituted Macrocyclic Diamides
title_short Efficient Synthesis of a Range of Benzosubstituted Macrocyclic Diamides
title_full Efficient Synthesis of a Range of Benzosubstituted Macrocyclic Diamides
title_fullStr Efficient Synthesis of a Range of Benzosubstituted Macrocyclic Diamides
title_full_unstemmed Efficient Synthesis of a Range of Benzosubstituted Macrocyclic Diamides
title_sort efficient synthesis of a range of benzosubstituted macrocyclic diamides
publisher Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series Iranian Journal of Chemistry & Chemical Engineering
issn 1021-9986
1021-9986
publishDate 2000-06-01
description Some new macrocyclic dibenzotetraoxadiamides, tribenzotetraoxadimides, tribenzopentaoxadiamide, tribenzohexaoxadiamide, and tetrabenzoheptaoxadiamide 15-22 have been prepared. These compounds were obtained in the macrocyclization step by reacting the diamines 6 and 7 with appropriate dicarboxylic acid dichlorides 8-14. The cyclization does not require high dilution techniques or template effect and provides the expected dilactams in high yields ranging from 63% to 81%.
topic macrocyclic diamides
synthesis
direct macrocyclization
dicarboxylic acid dichloride
url http://www.ijcce.ac.ir/article_10199_3f0816a9e5003cff873ee9a0e8775719.pdf
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AT khodabakhshniknam efficientsynthesisofarangeofbenzosubstitutedmacrocyclicdiamides
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