Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte
In this work, solid-state polymer supercapacitor (SSC) was assembled using poly(3,4-ethylenedioxythiophene/carbon paper (PEDOT/CP) as an electrode and ionic liquid (1-butyl-3-methylimidazole tetrafluoroborate)/polyvinyl alcohol/sulfuric acid (IL/PVA/H<sub>2</sub>SO<sub>4</sub>...
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doaj-9c4d6a9306e94c0f92f2c9123738f69a2020-11-25T01:40:00ZengMDPI AGPolymers2073-43602020-02-0112229710.3390/polym12020297polym12020297Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer ElectrolyteHaiyan Du0Zemin Wu1Yuyu Xu2Shaoze Liu3Huimin Yang4College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Yingze West Street 79, Taiyuan 030024, ChinaCollege of Chemistry and Chemical Engineering, Taiyuan University of Technology, Yingze West Street 79, Taiyuan 030024, ChinaCollege of Chemistry and Chemical Engineering, Taiyuan University of Technology, Yingze West Street 79, Taiyuan 030024, ChinaCollege of Chemistry and Chemical Engineering, Taiyuan University of Technology, Yingze West Street 79, Taiyuan 030024, ChinaCollege of Chemistry and Chemical Engineering, Taiyuan University of Technology, Yingze West Street 79, Taiyuan 030024, ChinaIn this work, solid-state polymer supercapacitor (SSC) was assembled using poly(3,4-ethylenedioxythiophene/carbon paper (PEDOT/CP) as an electrode and ionic liquid (1-butyl-3-methylimidazole tetrafluoroborate)/polyvinyl alcohol/sulfuric acid (IL/PVA/H<sub>2</sub>SO<sub>4</sub>) as a gel polymer electrolyte (GPE). The GPE was treated through freezing−thawing (F/T) cycles to improve the electrochemical properties of PEDOT SSC. Cyclic voltammetry (CV), galvanostatic charge−discharge measurements (GCD) and electrochemical impedance spectroscopy (EIS) techniques and conductivity were carried out to study the electrochemical performance. The results showed that the SSC based on ionic liquid GPE (SSC-IL/PVA/H<sub>2</sub>SO<sub>4</sub>) has a higher specific capacitance (with the value of 86.81 F/g at 1 mA/cm<sup>2</sup>) than the SSC-PVA/H<sub>2</sub>SO<sub>4</sub>.The number of F/T cycles has a great effect on the electrochemical performance of the device. The energy density of the SSC treated with 3 F/T cycles was significantly improved, reaching 176.90 Wh/kg. Compared with the traditional electrolytes, IL GPE has the advantages of high ionic conductivity, less volatility, non-flammability and wider potential window. Moreover, the IL GPE has excellent elastic recovery and self-healing performance, leading to its great potential applications in flexible or smart energy storage equipment.https://www.mdpi.com/2073-4360/12/2/297poly(3,4-ethylenedioxythiophene)1-butyl-3-methylimidazolium tetrafluoroborategel polymer electrolytesolid state supercapacitor |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Haiyan Du Zemin Wu Yuyu Xu Shaoze Liu Huimin Yang |
spellingShingle |
Haiyan Du Zemin Wu Yuyu Xu Shaoze Liu Huimin Yang Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte Polymers poly(3,4-ethylenedioxythiophene) 1-butyl-3-methylimidazolium tetrafluoroborate gel polymer electrolyte solid state supercapacitor |
author_facet |
Haiyan Du Zemin Wu Yuyu Xu Shaoze Liu Huimin Yang |
author_sort |
Haiyan Du |
title |
Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte |
title_short |
Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte |
title_full |
Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte |
title_fullStr |
Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte |
title_full_unstemmed |
Poly(3,4-ethylenedioxythiophene) Based Solid-State Polymer Supercapacitor with Ionic Liquid Gel Polymer Electrolyte |
title_sort |
poly(3,4-ethylenedioxythiophene) based solid-state polymer supercapacitor with ionic liquid gel polymer electrolyte |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2020-02-01 |
description |
In this work, solid-state polymer supercapacitor (SSC) was assembled using poly(3,4-ethylenedioxythiophene/carbon paper (PEDOT/CP) as an electrode and ionic liquid (1-butyl-3-methylimidazole tetrafluoroborate)/polyvinyl alcohol/sulfuric acid (IL/PVA/H<sub>2</sub>SO<sub>4</sub>) as a gel polymer electrolyte (GPE). The GPE was treated through freezing−thawing (F/T) cycles to improve the electrochemical properties of PEDOT SSC. Cyclic voltammetry (CV), galvanostatic charge−discharge measurements (GCD) and electrochemical impedance spectroscopy (EIS) techniques and conductivity were carried out to study the electrochemical performance. The results showed that the SSC based on ionic liquid GPE (SSC-IL/PVA/H<sub>2</sub>SO<sub>4</sub>) has a higher specific capacitance (with the value of 86.81 F/g at 1 mA/cm<sup>2</sup>) than the SSC-PVA/H<sub>2</sub>SO<sub>4</sub>.The number of F/T cycles has a great effect on the electrochemical performance of the device. The energy density of the SSC treated with 3 F/T cycles was significantly improved, reaching 176.90 Wh/kg. Compared with the traditional electrolytes, IL GPE has the advantages of high ionic conductivity, less volatility, non-flammability and wider potential window. Moreover, the IL GPE has excellent elastic recovery and self-healing performance, leading to its great potential applications in flexible or smart energy storage equipment. |
topic |
poly(3,4-ethylenedioxythiophene) 1-butyl-3-methylimidazolium tetrafluoroborate gel polymer electrolyte solid state supercapacitor |
url |
https://www.mdpi.com/2073-4360/12/2/297 |
work_keys_str_mv |
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