(Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)

(Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)

In the title compound, [Nb(CH3O)3(C5H7O2)Cl], the NbV atom is coordinated by two O atoms from the chelating acetylacetonate ligand, three O atoms from the methanolate groups and one chloride ligand. The octahedral environment around niobium is slightly distorted with Nb—O distances in...

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Main Authors: Leandra Herbst, Renier Koen, Andreas Roodt, Hendrik G. Visser
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810021719
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spelling doaj-9c545ed6527a4270a57a81a3def7edc62020-11-25T02:46:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m801m80210.1107/S1600536810021719(Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)Leandra HerbstRenier KoenAndreas RoodtHendrik G. VisserIn the title compound, [Nb(CH3O)3(C5H7O2)Cl], the NbV atom is coordinated by two O atoms from the chelating acetylacetonate ligand, three O atoms from the methanolate groups and one chloride ligand. The octahedral environment around niobium is slightly distorted with Nb—O distances in the range 1.8603 (15)–2.1083 (15) Å and an Nb—Cl distance of 2.4693 (9) Å. The O—Nb—O angles vary between 80.74 (6) and 100.82 (7)°, while the trans Cl—Nb—O angle is 167.60 (5)°. There are no hydrogen bonds observed, only an intermolecular C—H...O interaction. http://scripts.iucr.org/cgi-bin/paper?S1600536810021719
collection DOAJ
language English
format Article
sources DOAJ
author Leandra Herbst
Renier Koen
Andreas Roodt
Hendrik G. Visser
spellingShingle Leandra Herbst
Renier Koen
Andreas Roodt
Hendrik G. Visser
(Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)
Acta Crystallographica Section E
author_facet Leandra Herbst
Renier Koen
Andreas Roodt
Hendrik G. Visser
author_sort Leandra Herbst
title (Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)
title_short (Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)
title_full (Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)
title_fullStr (Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)
title_full_unstemmed (Acetylacetonato-κ2O,O′)chloridotrimethanolatoniobium(V)
title_sort (acetylacetonato-κ2o,o′)chloridotrimethanolatoniobium(v)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description In the title compound, [Nb(CH3O)3(C5H7O2)Cl], the NbV atom is coordinated by two O atoms from the chelating acetylacetonate ligand, three O atoms from the methanolate groups and one chloride ligand. The octahedral environment around niobium is slightly distorted with Nb—O distances in the range 1.8603 (15)–2.1083 (15) Å and an Nb—Cl distance of 2.4693 (9) Å. The O—Nb—O angles vary between 80.74 (6) and 100.82 (7)°, while the trans Cl—Nb—O angle is 167.60 (5)°. There are no hydrogen bonds observed, only an intermolecular C—H...O interaction.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810021719
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AT renierkoen acetylacetonatoamp9542ooamp8242chloridotrimethanolatoniobiumv
AT andreasroodt acetylacetonatoamp9542ooamp8242chloridotrimethanolatoniobiumv
AT hendrikgvisser acetylacetonatoamp9542ooamp8242chloridotrimethanolatoniobiumv
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