Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))

Isotactic poly (1-butene), ipbu-1, was synthesized by using a metallocene catalyst. The thermodynamic phase behavior of polymer–organic solvents systems is very important in every polymer application.  In this paper, the solid–liquid equilibrium of ipbu-1 with different organic solvents (1-heptyne,...

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Main Authors: Hossein Ghanadzadeh, Allahyar Daghbandan, Mohammd Akbarizadeh
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2014-03-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_7197_62a66b9e34c003a69c2eb5e8e49ac67b.pdf
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spelling doaj-9cabc1c23d1d47c790219e0a15da6cb52020-11-25T03:22:17ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862014-03-0133167737197Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))Hossein Ghanadzadeh0Allahyar Daghbandan1Mohammd Akbarizadeh2Department of Chemical Engineering, Faculty of Engineering,Guilan University , P.O. Box 4163-3756 Rasht, I.R. IRANDepartment of Chemical Engineering, Faculty of Engineering,Guilan University , P.O. Box 4163-3756 Rasht, I.R. IRANDepartment of Chemical Engineering, Faculty of Engineering,Guilan University , P.O. Box 4163-3756 Rasht, I.R. IRANIsotactic poly (1-butene), ipbu-1, was synthesized by using a metallocene catalyst. The thermodynamic phase behavior of polymer–organic solvents systems is very important in every polymer application.  In this paper, the solid–liquid equilibrium of ipbu-1 with different organic solvents (1-heptyne, cyclo octane) was studied by a mathematical model. By considering the experiments temperature-mole fraction results, phase diagram of the polymer solvent systems could be constructed. The temperature and activity coefficient based on mole fraction phase diagrams were predicted by using Pareto genetic design of GMDH-type neural network. The results were very encouraging and congruent with the experimental data.http://www.ijcce.ac.ir/article_7197_62a66b9e34c003a69c2eb5e8e49ac67b.pdfsolid-liquid equilibriumisotactic poly (1-butene)gmdh type-neural networkorganic solvents
collection DOAJ
language English
format Article
sources DOAJ
author Hossein Ghanadzadeh
Allahyar Daghbandan
Mohammd Akbarizadeh
spellingShingle Hossein Ghanadzadeh
Allahyar Daghbandan
Mohammd Akbarizadeh
Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))
Iranian Journal of Chemistry & Chemical Engineering
solid-liquid equilibrium
isotactic poly (1-butene)
gmdh type-neural network
organic solvents
author_facet Hossein Ghanadzadeh
Allahyar Daghbandan
Mohammd Akbarizadeh
author_sort Hossein Ghanadzadeh
title Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))
title_short Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))
title_full Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))
title_fullStr Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))
title_full_unstemmed Applying Pareto Design of GMDH-Type Neural Network for Solid-Liquid Equilibrium of Binary Systems (Isotactic Poly 1-Butene (1)-Organic Solvents (2))
title_sort applying pareto design of gmdh-type neural network for solid-liquid equilibrium of binary systems (isotactic poly 1-butene (1)-organic solvents (2))
publisher Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series Iranian Journal of Chemistry & Chemical Engineering
issn 1021-9986
1021-9986
publishDate 2014-03-01
description Isotactic poly (1-butene), ipbu-1, was synthesized by using a metallocene catalyst. The thermodynamic phase behavior of polymer–organic solvents systems is very important in every polymer application.  In this paper, the solid–liquid equilibrium of ipbu-1 with different organic solvents (1-heptyne, cyclo octane) was studied by a mathematical model. By considering the experiments temperature-mole fraction results, phase diagram of the polymer solvent systems could be constructed. The temperature and activity coefficient based on mole fraction phase diagrams were predicted by using Pareto genetic design of GMDH-type neural network. The results were very encouraging and congruent with the experimental data.
topic solid-liquid equilibrium
isotactic poly (1-butene)
gmdh type-neural network
organic solvents
url http://www.ijcce.ac.ir/article_7197_62a66b9e34c003a69c2eb5e8e49ac67b.pdf
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