Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction
A theory of the mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of electro-inactive chemical reacta...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
PURKH
2019-04-01
|
Series: | To Chemistry Journal |
Subjects: | |
Online Access: | https://www.purkh.com/index.php/tochem/article/view/350 |
id |
doaj-9d2d882f2a3043c0bbdbaa8591211041 |
---|---|
record_format |
Article |
spelling |
doaj-9d2d882f2a3043c0bbdbaa85912110412020-11-25T03:37:36ZengPURKHTo Chemistry Journal2581-75072019-04-012Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical ReactionMilivoj Lovrić0Šebojka Komorsky-LovrićŠebojka Komorsky-Lovrić and Milivoj Lovrić Divkovićeva 13, A theory of the mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of electro-inactive chemical reactant on the responses are investigated for thermodynamically stable intermediate. The limits of three types of responses are calculated and the formula for the estimation of the forward rate constant of chemical reaction is proposed. https://www.purkh.com/index.php/tochem/article/view/350ECE MechanismSquare Wave VoltammetryTheoryKineticsEquilibrium Conditions |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Milivoj Lovrić Šebojka Komorsky-Lovrić |
spellingShingle |
Milivoj Lovrić Šebojka Komorsky-Lovrić Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction To Chemistry Journal ECE Mechanism Square Wave Voltammetry Theory Kinetics Equilibrium Conditions |
author_facet |
Milivoj Lovrić Šebojka Komorsky-Lovrić |
author_sort |
Milivoj Lovrić |
title |
Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction |
title_short |
Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction |
title_full |
Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction |
title_fullStr |
Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction |
title_full_unstemmed |
Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction |
title_sort |
theory of square wave voltammetry of two reversible electrode reactions connected by the reversible chemical reaction |
publisher |
PURKH |
series |
To Chemistry Journal |
issn |
2581-7507 |
publishDate |
2019-04-01 |
description |
A theory of the mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of electro-inactive chemical reactant on the responses are investigated for thermodynamically stable intermediate. The limits of three types of responses are calculated and the formula for the estimation of the forward rate constant of chemical reaction is proposed.
|
topic |
ECE Mechanism Square Wave Voltammetry Theory Kinetics Equilibrium Conditions |
url |
https://www.purkh.com/index.php/tochem/article/view/350 |
work_keys_str_mv |
AT milivojlovric theoryofsquarewavevoltammetryoftworeversibleelectrodereactionsconnectedbythereversiblechemicalreaction AT sebojkakomorskylovric theoryofsquarewavevoltammetryoftworeversibleelectrodereactionsconnectedbythereversiblechemicalreaction |
_version_ |
1724545020545990656 |