Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction

Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction

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A theory of the mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of electro-inactive chemical reacta...

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Main Authors: Milivoj Lovrić, Šebojka Komorsky-Lovrić
Format: Article
Language:English
Published: PURKH 2019-04-01
Series:To Chemistry Journal
Subjects:
ECE Mechanism
Square Wave Voltammetry
Theory
Kinetics
Equilibrium Conditions
Online Access:https://www.purkh.com/index.php/tochem/article/view/350
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spelling doaj-9d2d882f2a3043c0bbdbaa85912110412020-11-25T03:37:36ZengPURKHTo Chemistry Journal2581-75072019-04-012Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical ReactionMilivoj Lovrić0Šebojka Komorsky-LovrićŠebojka Komorsky-Lovrić and Milivoj Lovrić Divkovićeva 13, A theory of the mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of electro-inactive chemical reactant on the responses are investigated for thermodynamically stable intermediate. The limits of three types of responses are calculated and the formula for the estimation of the forward rate constant of chemical reaction is proposed. https://www.purkh.com/index.php/tochem/article/view/350ECE MechanismSquare Wave VoltammetryTheoryKineticsEquilibrium Conditions
collection DOAJ
language English
format Article
sources DOAJ
author Milivoj Lovrić
Šebojka Komorsky-Lovrić
spellingShingle Milivoj Lovrić
Šebojka Komorsky-Lovrić
Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction
To Chemistry Journal
ECE Mechanism
Square Wave Voltammetry
Theory
Kinetics
Equilibrium Conditions
author_facet Milivoj Lovrić
Šebojka Komorsky-Lovrić
author_sort Milivoj Lovrić
title Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction
title_short Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction
title_full Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction
title_fullStr Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction
title_full_unstemmed Theory of Square Wave Voltammetry of Two Reversible Electrode Reactions Connected by The Reversible Chemical Reaction
title_sort theory of square wave voltammetry of two reversible electrode reactions connected by the reversible chemical reaction
publisher PURKH
series To Chemistry Journal
issn 2581-7507
publishDate 2019-04-01
description A theory of the mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of electro-inactive chemical reactant on the responses are investigated for thermodynamically stable intermediate. The limits of three types of responses are calculated and the formula for the estimation of the forward rate constant of chemical reaction is proposed.
topic ECE Mechanism
Square Wave Voltammetry
Theory
Kinetics
Equilibrium Conditions
url https://www.purkh.com/index.php/tochem/article/view/350
work_keys_str_mv AT milivojlovric theoryofsquarewavevoltammetryoftworeversibleelectrodereactionsconnectedbythereversiblechemicalreaction
AT sebojkakomorskylovric theoryofsquarewavevoltammetryoftworeversibleelectrodereactionsconnectedbythereversiblechemicalreaction
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