Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1)
The asymmetric unit of the title compound, [Co(NCS)2(C6H6N2O)4]·2C6H6N2O·C2H5OH, comprises one CoII cation, two thiocyanate anions, four coordinating and two solvent isonicotinamide molecules and one ethanol solvent molecule. The CoII cations are octahedrally coordinated by four N-coordinating isoni...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2016-08-01
|
Series: | Acta Crystallographica Section E: Crystallographic Communications |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016010951 |
id |
doaj-9f1e2a1091a14145b367d0ce1af5ec0e |
---|---|
record_format |
Article |
spelling |
doaj-9f1e2a1091a14145b367d0ce1af5ec0e2020-11-24T22:43:43ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-08-017281077108010.1107/S2056989016010951wm5305Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1)Tristan Neumann0Inke Jess1Christian Näther2Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyInstitut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, GermanyThe asymmetric unit of the title compound, [Co(NCS)2(C6H6N2O)4]·2C6H6N2O·C2H5OH, comprises one CoII cation, two thiocyanate anions, four coordinating and two solvent isonicotinamide molecules and one ethanol solvent molecule. The CoII cations are octahedrally coordinated by four N-coordinating isonicotinamide ligands and two terminally N-bonded thiocyanate anions. These discrete complexes are linked by intermolecular N—H...O and N—H...S hydrogen-bonding interactions into a three-dimensional network. The two isonicotinamide and the ethanol solvent molecules are embedded in channels of this network and are linked through further N—H...O and N—H...N hydrogen bonds to the network. The ethanol solvent molecule is disordered over two sets of sites (occupancy ratio 0.6:0.4).http://scripts.iucr.org/cgi-bin/paper?S2056989016010951crystal structurehydrogen bondingisonicotinamidecobalt |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Tristan Neumann Inke Jess Christian Näther |
spellingShingle |
Tristan Neumann Inke Jess Christian Näther Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1) Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen bonding isonicotinamide cobalt |
author_facet |
Tristan Neumann Inke Jess Christian Näther |
author_sort |
Tristan Neumann |
title |
Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1) |
title_short |
Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1) |
title_full |
Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1) |
title_fullStr |
Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1) |
title_full_unstemmed |
Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1) |
title_sort |
crystal structure of tetrakis(isonicotinamide-κn)bis(thiocyanato-κn)cobalt(ii)–isonicotinamide–ethanol (1/2/1) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2016-08-01 |
description |
The asymmetric unit of the title compound, [Co(NCS)2(C6H6N2O)4]·2C6H6N2O·C2H5OH, comprises one CoII cation, two thiocyanate anions, four coordinating and two solvent isonicotinamide molecules and one ethanol solvent molecule. The CoII cations are octahedrally coordinated by four N-coordinating isonicotinamide ligands and two terminally N-bonded thiocyanate anions. These discrete complexes are linked by intermolecular N—H...O and N—H...S hydrogen-bonding interactions into a three-dimensional network. The two isonicotinamide and the ethanol solvent molecules are embedded in channels of this network and are linked through further N—H...O and N—H...N hydrogen bonds to the network. The ethanol solvent molecule is disordered over two sets of sites (occupancy ratio 0.6:0.4). |
topic |
crystal structure hydrogen bonding isonicotinamide cobalt |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989016010951 |
work_keys_str_mv |
AT tristanneumann crystalstructureoftetrakisisonicotinamideknbisthiocyanatokncobaltiiisonicotinamideethanol121 AT inkejess crystalstructureoftetrakisisonicotinamideknbisthiocyanatokncobaltiiisonicotinamideethanol121 AT christiannather crystalstructureoftetrakisisonicotinamideknbisthiocyanatokncobaltiiisonicotinamideethanol121 |
_version_ |
1725695028806811648 |