Structural characterization of heterometallic platinum complexes with non-transition metals. Part V: Heterooligo- and heteropolynuclear complexes
This review classifies and analyzes heterooligo- and heteropolynuclear Pt complexes in the presence of non-transition metals as partners. There is a wide variability of metal combinations: Pt6M, Pt2M5, Pt3Hg2Ru2; Pt6M2, Pt4Zn4, Pt2Hg6, PtHgAu6, PtHg2Au5; Pt6Hg4, Pt3HgRu6, PtHgAu8; Pt2Sn9, PtHg2Au8;...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2013-12-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2013-0028 |
| Summary: | This review classifies and analyzes heterooligo- and heteropolynuclear Pt complexes in the presence of non-transition metals as partners. There is a wide variability of metal combinations: Pt6M, Pt2M5, Pt3Hg2Ru2; Pt6M2, Pt4Zn4, Pt2Hg6, PtHgAu6, PtHg2Au5; Pt6Hg4, Pt3HgRu6, PtHgAu8; Pt2Sn9, PtHg2Au8; Pt8Ge4, Pt8Sn4 and {PtM}n. The complexes crystallized in the following crystal classes: trigonal, orthorhombic (each 1 example)<tetragonal (6 examples)<triclinic (15 examples)<monoclinic (19 examples). The mean Pt-Pt bond length is 2.770 Å. The mean Pt-M bond length increased in the order 2.430 Å (M=Ga)<2.685 Å (Ge)<2.770 Å (Zn)<2.822 Å (Sn)<2.834 Å (Hg)<2.932 Å (Tl). This review together with the previous parts gives a comprehensive view on heterometallic Pt complexes with non-transition metals. |
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| ISSN: | 0792-1241 2191-0219 |