Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides
In a one-step procedure, various β-bromoalcohols were synthesized from natural terpenes in good to excellent yields. Using different catalysts, the reaction was carried out at room temperature, with H2O as nucleophile and N-bromosuccinimide as a bromine source under mild reaction conditions. The syn...
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Hindawi Limited
2019-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2019/9268567 |
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doaj-9fbd98611faf4fa0a3a858bc263c46e12020-11-25T02:44:56ZengHindawi LimitedJournal of Chemistry2090-90632090-90712019-01-01201910.1155/2019/92685679268567Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic EpoxidesSaadia Oubaassine0Angela Köckritz1Reinhard Eckelt2Andreas Martin3Mustapha Ait Ali4Larbi El Firdoussi5Leibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyLeibniz-Institut für Katalyse e. V. (LIKAT Rostock), Albert-Einstein-Str. 29 a, 18059 Rostock, GermanyDepartment of Chemistry, Equipe de Chimie de Coordination et Catalyse, Faculty of Sciences Semlalia, Cadi Ayyad University, P.O. Box: 2390, 40001 Marrakech, MoroccoDepartment of Chemistry, Equipe de Chimie de Coordination et Catalyse, Faculty of Sciences Semlalia, Cadi Ayyad University, P.O. Box: 2390, 40001 Marrakech, MoroccoIn a one-step procedure, various β-bromoalcohols were synthesized from natural terpenes in good to excellent yields. Using different catalysts, the reaction was carried out at room temperature, with H2O as nucleophile and N-bromosuccinimide as a bromine source under mild reaction conditions. The synthesized β-bromoalcohols were subsequently converted in situ to the corresponding epoxides in good yields.http://dx.doi.org/10.1155/2019/9268567 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Saadia Oubaassine Angela Köckritz Reinhard Eckelt Andreas Martin Mustapha Ait Ali Larbi El Firdoussi |
| spellingShingle |
Saadia Oubaassine Angela Köckritz Reinhard Eckelt Andreas Martin Mustapha Ait Ali Larbi El Firdoussi Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides Journal of Chemistry |
| author_facet |
Saadia Oubaassine Angela Köckritz Reinhard Eckelt Andreas Martin Mustapha Ait Ali Larbi El Firdoussi |
| author_sort |
Saadia Oubaassine |
| title |
Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_short |
Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_full |
Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_fullStr |
Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_full_unstemmed |
Catalytic β-Bromohydroxylation of Natural Terpenes: Useful Intermediates for the Synthesis of Terpenic Epoxides |
| title_sort |
catalytic β-bromohydroxylation of natural terpenes: useful intermediates for the synthesis of terpenic epoxides |
| publisher |
Hindawi Limited |
| series |
Journal of Chemistry |
| issn |
2090-9063 2090-9071 |
| publishDate |
2019-01-01 |
| description |
In a one-step procedure, various β-bromoalcohols were synthesized from natural terpenes in good to excellent yields. Using different catalysts, the reaction was carried out at room temperature, with H2O as nucleophile and N-bromosuccinimide as a bromine source under mild reaction conditions. The synthesized β-bromoalcohols were subsequently converted in situ to the corresponding epoxides in good yields. |
| url |
http://dx.doi.org/10.1155/2019/9268567 |
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