Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
In the title molecular salt, C12H12N22+·2C7H5O5S−, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carboxylic acid group and the benzene ring is 12.41 (11)°. In the cryst...
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doaj-9fdab1e7f9af47debd1700af073080602020-11-25T01:27:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-11-017011o1170o117010.1107/S1600536814022673hb7296Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)Jing Wu0Long-Guan Zhu1Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, People's Republic of ChinaDepartment of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, People's Republic of ChinaIn the title molecular salt, C12H12N22+·2C7H5O5S−, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carboxylic acid group and the benzene ring is 12.41 (11)°. In the crystal, the anions are linked into inversion dimers by pairs of O—H...O hydrogen bonds, which generate R22(16) loops. The dications link the anion dimers into [10-2] chains via N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536814022673crystal structure3-sulfobenzoate1,2-bis(pyridin-4-yl)ethylenehydrogen bonding4,4′-(ethane-1,2-diyl)dipyridinium |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Jing Wu Long-Guan Zhu |
spellingShingle |
Jing Wu Long-Guan Zhu Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate) Acta Crystallographica Section E crystal structure 3-sulfobenzoate 1,2-bis(pyridin-4-yl)ethylene hydrogen bonding 4,4′-(ethane-1,2-diyl)dipyridinium |
author_facet |
Jing Wu Long-Guan Zhu |
author_sort |
Jing Wu |
title |
Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate) |
title_short |
Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate) |
title_full |
Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate) |
title_fullStr |
Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate) |
title_full_unstemmed |
Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate) |
title_sort |
crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2014-11-01 |
description |
In the title molecular salt, C12H12N22+·2C7H5O5S−, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carboxylic acid group and the benzene ring is 12.41 (11)°. In the crystal, the anions are linked into inversion dimers by pairs of O—H...O hydrogen bonds, which generate R22(16) loops. The dications link the anion dimers into [10-2] chains via N—H...O hydrogen bonds. |
topic |
crystal structure 3-sulfobenzoate 1,2-bis(pyridin-4-yl)ethylene hydrogen bonding 4,4′-(ethane-1,2-diyl)dipyridinium |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814022673 |
work_keys_str_mv |
AT jingwu crystalstructureof44ethene12diyldipyridiniumbis3carboxybenzenesulfonate AT longguanzhu crystalstructureof44ethene12diyldipyridiniumbis3carboxybenzenesulfonate |
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1725106536473165824 |