Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)

Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)

In the title molecular salt, C12H12N22+·2C7H5O5S−, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carboxylic acid group and the benzene ring is 12.41 (11)°. In the cryst...

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Main Authors: Jing Wu, Long-Guan Zhu
Format: Article
Language:English
Published: International Union of Crystallography 2014-11-01
Series:Acta Crystallographica Section E
Subjects:
crystal structure
3-sulfobenzoate
1,2-bis(pyridin-4-yl)ethylene
hydrogen bonding
4,4′-(ethane-1,2-diyl)dipyridinium
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814022673
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spelling doaj-9fdab1e7f9af47debd1700af073080602020-11-25T01:27:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-11-017011o1170o117010.1107/S1600536814022673hb7296Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)Jing Wu0Long-Guan Zhu1Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, People's Republic of ChinaDepartment of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027, People's Republic of ChinaIn the title molecular salt, C12H12N22+·2C7H5O5S−, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carboxylic acid group and the benzene ring is 12.41 (11)°. In the crystal, the anions are linked into inversion dimers by pairs of O—H...O hydrogen bonds, which generate R22(16) loops. The dications link the anion dimers into [10-2] chains via N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536814022673crystal structure3-sulfobenzoate1,2-bis(pyridin-4-yl)ethylenehydrogen bonding4,4′-(ethane-1,2-diyl)dipyridinium
collection DOAJ
language English
format Article
sources DOAJ
author Jing Wu
Long-Guan Zhu
spellingShingle Jing Wu
Long-Guan Zhu
Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
Acta Crystallographica Section E
crystal structure
3-sulfobenzoate
1,2-bis(pyridin-4-yl)ethylene
hydrogen bonding
4,4′-(ethane-1,2-diyl)dipyridinium
author_facet Jing Wu
Long-Guan Zhu
author_sort Jing Wu
title Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
title_short Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
title_full Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
title_fullStr Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
title_full_unstemmed Crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
title_sort crystal structure of 4,4′-(ethene-1,2-diyl)dipyridinium bis(3-carboxybenzenesulfonate)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-11-01
description In the title molecular salt, C12H12N22+·2C7H5O5S−, the complete dication is generated by crystallographic inversion symmetry. In the anion, the sulfonic acid group is deprotonated and the dihedral angle between the planes of the carboxylic acid group and the benzene ring is 12.41 (11)°. In the crystal, the anions are linked into inversion dimers by pairs of O—H...O hydrogen bonds, which generate R22(16) loops. The dications link the anion dimers into [10-2] chains via N—H...O hydrogen bonds.
topic crystal structure
3-sulfobenzoate
1,2-bis(pyridin-4-yl)ethylene
hydrogen bonding
4,4′-(ethane-1,2-diyl)dipyridinium
url http://scripts.iucr.org/cgi-bin/paper?S1600536814022673
work_keys_str_mv AT jingwu crystalstructureof44ethene12diyldipyridiniumbis3carboxybenzenesulfonate
AT longguanzhu crystalstructureof44ethene12diyldipyridiniumbis3carboxybenzenesulfonate
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