5,5′-Thiobis(3-methoxy-4H-1,2,6-thiadiazin-4-one)

The reaction of 3-chloro-5-methoxy-4H-1,2,6-thiadiazin-4-one (9) with Na2S·9H2O (0.5 equiv) in tetrahydrofuran (THF) at ca. 20 °C for 20 h gives 5,5′-thiobis(3-methoxy-4H...

Full description

Bibliographic Details
Main Authors:	Andreas S. Kalogirou, Panayiotis A. Koutentis
Format:	Article
Language:	English
Published:	MDPI AG 2019-06-01
Series:	Molbank
Subjects:	heterocycle 1,2,6-thiadiazine sulfide nucleophilic displacement
Online Access:	https://www.mdpi.com/1422-8599/2019/2/M1064

id	doaj-a08d892e07a74ea3b40f3b287fc081e2
record_format	Article
spelling	doaj-a08d892e07a74ea3b40f3b287fc081e22020-11-25T02:14:49ZengMDPI AGMolbank1422-85992019-06-0120192M106410.3390/M1064M10645,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one)Andreas S. Kalogirou0Panayiotis A. Koutentis1Department of Life Sciences, School of Sciences, European University Cyprus, 6 Diogenis Str., Engomi, P.O. Box 22006, 1516 Nicosia, CyprusDepartment of Chemistry, University of Cyprus, P.O. Box 20537, 1678 Nicosia, CyprusThe reaction of 3-chloro-5-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one (<b>9</b>) with Na<sub>2</sub>S·9H<sub>2</sub>O (0.5 equiv) in tetrahydrofuran (THF) at ca. 20 °C for 20 h gives 5,5′-thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one) (<b>10</b>) in a 44% yield as yellow needles. The compound was fully characterized.https://www.mdpi.com/1422-8599/2019/2/M1064heterocycle1,2,6-thiadiazinesulfidenucleophilic displacement
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Andreas S. Kalogirou Panayiotis A. Koutentis
spellingShingle	Andreas S. Kalogirou Panayiotis A. Koutentis 5,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one) Molbank heterocycle 1,2,6-thiadiazine sulfide nucleophilic displacement
author_facet	Andreas S. Kalogirou Panayiotis A. Koutentis
author_sort	Andreas S. Kalogirou
title	5,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one)
title_short	5,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one)
title_full	5,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one)
title_fullStr	5,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one)
title_full_unstemmed	5,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one)
title_sort	5,5′-thiobis(3-methoxy-4<i>h</i>-1,2,6-thiadiazin-4-one)
publisher	MDPI AG
series	Molbank
issn	1422-8599
publishDate	2019-06-01
description	The reaction of 3-chloro-5-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one (<b>9</b>) with Na<sub>2</sub>S·9H<sub>2</sub>O (0.5 equiv) in tetrahydrofuran (THF) at ca. 20 °C for 20 h gives 5,5′-thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one) (<b>10</b>) in a 44% yield as yellow needles. The compound was fully characterized.
topic	heterocycle 1,2,6-thiadiazine sulfide nucleophilic displacement
url	https://www.mdpi.com/1422-8599/2019/2/M1064
work_keys_str_mv	AT andreasskalogirou 55thiobis3methoxy4ihi126thiadiazin4one AT panayiotisakoutentis 55thiobis3methoxy4ihi126thiadiazin4one
_version_	1724899498925228032

5,5′-Thiobis(3-methoxy-4<i>H</i>-1,2,6-thiadiazin-4-one)

Similar Items