Silver indium diphosphate, AgInP2O7

Silver indium diphosphate, AgInP2O7

Polycrystalline material of the title compound, AgInP2O7, was synthesized by traditional high-temperature solid-state methods and single crystals were grown from the melt of a mixture of AgInP2O7 and B2O3 as flux in a platinium crucible. The structure consists of InO6 octahedra, which are corner-sha...

Full description

Bibliographic Details
Main Authors: Lehcen El Ammari, Boujemaa Jaber, Mohamed Saadi, Hafid Zouihri
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810052451
id doaj-a0b21e48899c4faea07816b63534e029
record_format Article
spelling doaj-a0b21e48899c4faea07816b63534e0292020-11-25T01:56:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-01-01671i2i210.1107/S1600536810052451Silver indium diphosphate, AgInP2O7Lehcen El AmmariBoujemaa JaberMohamed SaadiHafid ZouihriPolycrystalline material of the title compound, AgInP2O7, was synthesized by traditional high-temperature solid-state methods and single crystals were grown from the melt of a mixture of AgInP2O7 and B2O3 as flux in a platinium crucible. The structure consists of InO6 octahedra, which are corner-shared to PO4 tetrahedra into a three-dimensional network with hexagonal channels running parallel to the c axis. The silver cation, located in the channel, is bonded to seven O atoms of the [InP2O7] framework with Ag–O distances ranging from 2.370 (2) to 3.015 (2) Å. The P2O7 diphosphate anion is characterized by a P—O—P angle of 137.27 (9) and a nearly eclipsed conformation. AgInP2O7 is isotypic with the MIFeP2O7 (MI = Na, K, Rb, Cs and Ag) diphosphate family. http://scripts.iucr.org/cgi-bin/paper?S1600536810052451
collection DOAJ
language English
format Article
sources DOAJ
author Lehcen El Ammari
Boujemaa Jaber
Mohamed Saadi
Hafid Zouihri
spellingShingle Lehcen El Ammari
Boujemaa Jaber
Mohamed Saadi
Hafid Zouihri
Silver indium diphosphate, AgInP2O7
Acta Crystallographica Section E
author_facet Lehcen El Ammari
Boujemaa Jaber
Mohamed Saadi
Hafid Zouihri
author_sort Lehcen El Ammari
title Silver indium diphosphate, AgInP2O7
title_short Silver indium diphosphate, AgInP2O7
title_full Silver indium diphosphate, AgInP2O7
title_fullStr Silver indium diphosphate, AgInP2O7
title_full_unstemmed Silver indium diphosphate, AgInP2O7
title_sort silver indium diphosphate, aginp2o7
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-01-01
description Polycrystalline material of the title compound, AgInP2O7, was synthesized by traditional high-temperature solid-state methods and single crystals were grown from the melt of a mixture of AgInP2O7 and B2O3 as flux in a platinium crucible. The structure consists of InO6 octahedra, which are corner-shared to PO4 tetrahedra into a three-dimensional network with hexagonal channels running parallel to the c axis. The silver cation, located in the channel, is bonded to seven O atoms of the [InP2O7] framework with Ag–O distances ranging from 2.370 (2) to 3.015 (2) Å. The P2O7 diphosphate anion is characterized by a P—O—P angle of 137.27 (9) and a nearly eclipsed conformation. AgInP2O7 is isotypic with the MIFeP2O7 (MI = Na, K, Rb, Cs and Ag) diphosphate family.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810052451
work_keys_str_mv AT lehcenelammari silverindiumdiphosphateaginp2o7
AT boujemaajaber silverindiumdiphosphateaginp2o7
AT mohamedsaadi silverindiumdiphosphateaginp2o7
AT hafidzouihri silverindiumdiphosphateaginp2o7
_version_ 1724978833165123584

Similar Items