Ultrafast spin crossover in a single crystal
Femtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution. Preliminary electron diffraction experiments show evidence of ultrafast Fe-N bond...
Main Authors: | , , , , , |
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Format: | Article |
Language: | English |
Published: |
EDP Sciences
2019-01-01
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Series: | EPJ Web of Conferences |
Online Access: | https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_07009.pdf |
Summary: | Femtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution. Preliminary electron diffraction experiments show evidence of ultrafast Fe-N bond elongation associated with spin crossover and the subsequent molecular reorganization resulting from vibrational cooling. |
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ISSN: | 2100-014X |