Ultrafast spin crossover in a single crystal

Ultrafast spin crossover in a single crystal

Femtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution. Preliminary electron diffraction experiments show evidence of ultrafast Fe-N bond...

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Main Authors: Field Ryan L., Liu Lai Chung, Jiang Yifeng, Gawelda Wojciech, Lu Cheng, Miller R. J. Dwayne
Format: Article
Language:English
Published: EDP Sciences 2019-01-01
Series:EPJ Web of Conferences
Online Access:https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_07009.pdf
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spelling doaj-a1365b2188254b8e917b3dde3101e6642021-08-02T04:01:02ZengEDP SciencesEPJ Web of Conferences2100-014X2019-01-012050700910.1051/epjconf/201920507009epjconf_up2019_07009Ultrafast spin crossover in a single crystalField Ryan L.Liu Lai ChungJiang YifengGawelda Wojciech0Lu Cheng1Miller R. J. Dwayne2European XFEL GmbHDepartments of Chemistry and Physics, University of TorontoDepartments of Chemistry and Physics, University of TorontoFemtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution. Preliminary electron diffraction experiments show evidence of ultrafast Fe-N bond elongation associated with spin crossover and the subsequent molecular reorganization resulting from vibrational cooling.https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_07009.pdf
collection DOAJ
language English
format Article
sources DOAJ
author Field Ryan L.
Liu Lai Chung
Jiang Yifeng
Gawelda Wojciech
Lu Cheng
Miller R. J. Dwayne
spellingShingle Field Ryan L.
Liu Lai Chung
Jiang Yifeng
Gawelda Wojciech
Lu Cheng
Miller R. J. Dwayne
Ultrafast spin crossover in a single crystal
EPJ Web of Conferences
author_facet Field Ryan L.
Liu Lai Chung
Jiang Yifeng
Gawelda Wojciech
Lu Cheng
Miller R. J. Dwayne
author_sort Field Ryan L.
title Ultrafast spin crossover in a single crystal
title_short Ultrafast spin crossover in a single crystal
title_full Ultrafast spin crossover in a single crystal
title_fullStr Ultrafast spin crossover in a single crystal
title_full_unstemmed Ultrafast spin crossover in a single crystal
title_sort ultrafast spin crossover in a single crystal
publisher EDP Sciences
series EPJ Web of Conferences
issn 2100-014X
publishDate 2019-01-01
description Femtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution. Preliminary electron diffraction experiments show evidence of ultrafast Fe-N bond elongation associated with spin crossover and the subsequent molecular reorganization resulting from vibrational cooling.
url https://www.epj-conferences.org/articles/epjconf/pdf/2019/10/epjconf_up2019_07009.pdf
work_keys_str_mv AT fieldryanl ultrafastspincrossoverinasinglecrystal
AT liulaichung ultrafastspincrossoverinasinglecrystal
AT jiangyifeng ultrafastspincrossoverinasinglecrystal
AT gaweldawojciech ultrafastspincrossoverinasinglecrystal
AT lucheng ultrafastspincrossoverinasinglecrystal
AT millerrjdwayne ultrafastspincrossoverinasinglecrystal
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