Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates
The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.
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2002-08-01
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Online Access: | http://www.mdpi.com/1420-3049/7/8/601/ |
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doaj-a2b90ede0f3f4e7588706cdba07e59fa2020-11-25T00:44:14ZengMDPI AGMolecules1420-30492002-08-017860161710.3390/70800601Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl SulfonatesPatrick BohrerThomas NetscherThe trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.http://www.mdpi.com/1420-3049/7/8/601/Alkylation reagentsSN2 substitution reactionssteric hindrancesulfonic esterssulfur-oxygen bond cleavage. |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Patrick Bohrer Thomas Netscher |
spellingShingle |
Patrick Bohrer Thomas Netscher Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates Molecules Alkylation reagents SN2 substitution reactions steric hindrance sulfonic esters sulfur-oxygen bond cleavage. |
author_facet |
Patrick Bohrer Thomas Netscher |
author_sort |
Patrick Bohrer |
title |
Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates |
title_short |
Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates |
title_full |
Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates |
title_fullStr |
Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates |
title_full_unstemmed |
Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates |
title_sort |
towards highly activating leaving groups: studies on the preparation of some halogenated alkyl sulfonates |
publisher |
MDPI AG |
series |
Molecules |
issn |
1420-3049 |
publishDate |
2002-08-01 |
description |
The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed. |
topic |
Alkylation reagents SN2 substitution reactions steric hindrance sulfonic esters sulfur-oxygen bond cleavage. |
url |
http://www.mdpi.com/1420-3049/7/8/601/ |
work_keys_str_mv |
AT patrickbohrer towardshighlyactivatingleavinggroupsstudiesonthepreparationofsomehalogenatedalkylsulfonates AT thomasnetscher towardshighlyactivatingleavinggroupsstudiesonthepreparationofsomehalogenatedalkylsulfonates |
_version_ |
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