Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates

The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.

Bibliographic Details
Main Authors:	Patrick Bohrer, Thomas Netscher
Format:	Article
Language:	English
Published:	MDPI AG 2002-08-01
Series:	Molecules
Subjects:	Alkylation reagents SN2 substitution reactions steric hindrance sulfonic esters sulfur-oxygen bond cleavage.
Online Access:	http://www.mdpi.com/1420-3049/7/8/601/

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spelling	doaj-a2b90ede0f3f4e7588706cdba07e59fa2020-11-25T00:44:14ZengMDPI AGMolecules1420-30492002-08-017860161710.3390/70800601Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl SulfonatesPatrick BohrerThomas NetscherThe trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.http://www.mdpi.com/1420-3049/7/8/601/Alkylation reagentsSN2 substitution reactionssteric hindrancesulfonic esterssulfur-oxygen bond cleavage.
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Patrick Bohrer Thomas Netscher
spellingShingle	Patrick Bohrer Thomas Netscher Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates Molecules Alkylation reagents SN2 substitution reactions steric hindrance sulfonic esters sulfur-oxygen bond cleavage.
author_facet	Patrick Bohrer Thomas Netscher
author_sort	Patrick Bohrer
title	Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates
title_short	Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates
title_full	Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates
title_fullStr	Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates
title_full_unstemmed	Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates
title_sort	towards highly activating leaving groups: studies on the preparation of some halogenated alkyl sulfonates
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2002-08-01
description	The trichloromethylsulfonyl-, dichloromethylsulfonyl-, chlorosulfonyl-, and fluorosulfonyl esters of a neopentyl-type alcohol have been prepared via sulfonylation or sulfinylation followed by oxidation. The preparative usefulness and potential of the transformations are discussed.
topic	Alkylation reagents SN2 substitution reactions steric hindrance sulfonic esters sulfur-oxygen bond cleavage.
url	http://www.mdpi.com/1420-3049/7/8/601/
work_keys_str_mv	AT patrickbohrer towardshighlyactivatingleavinggroupsstudiesonthepreparationofsomehalogenatedalkylsulfonates AT thomasnetscher towardshighlyactivatingleavinggroupsstudiesonthepreparationofsomehalogenatedalkylsulfonates
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Towards Highly Activating Leaving Groups: Studies on the Preparation of Some Halogenated Alkyl Sulfonates

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