Tris(4-methoxyphenyl)phosphine selenide

Tris(4-methoxyphenyl)phosphine selenide

The title compound, C21H21O3PSe, is comprised of a P atom in a distorted tetrahedral environment, attached to the Se atom and three C atoms of the phenyl rings. The P—Se bond length is 2.1214 (12) Å. All three methoxy groups are near coplanar with their respective phenyl rings, with the angles betwe...

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Bibliographic Details
Main Authors: Melina Raymundo, Clifford W. Padgett, Will E. Lynch
Format: Article
Language:English
Published: International Union of Crystallography 2016-08-01
Series:IUCrData
Subjects:
crystal structure
tris(4-methoxyphenyl)phosphine selenide
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616012712
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spelling doaj-a376f4abbabe4315a7f5ce474379c06e2020-11-24T22:57:01ZengInternational Union of CrystallographyIUCrData2414-31462016-08-0118x16127110.1107/S2414314616012712pk4008Tris(4-methoxyphenyl)phosphine selenideMelina Raymundo0Clifford W. Padgett1Will E. Lynch2Department of Chemistry and Physics, Armstrong State University, Savannah, GA 31419, USADepartment of Chemistry and Physics, Armstrong State University, Savannah, GA 31419, USADepartment of Chemistry and Physics, Armstrong State University, Savannah, GA 31419, USAThe title compound, C21H21O3PSe, is comprised of a P atom in a distorted tetrahedral environment, attached to the Se atom and three C atoms of the phenyl rings. The P—Se bond length is 2.1214 (12) Å. All three methoxy groups are near coplanar with their respective phenyl rings, with the angles between the phenyl ring and the C—O bond of the methoxy groups being 5.7 (2), 1.5 (4), and 5.7 (3)°. The torsion angles of the phenyl rings relative to the P=Se bond are 35.62 (10), 35.07 (13), and 44.50 (11)°. No strong intermolecular interactions were observed, but that in addition to van der Waals forces, there are C—H...π and C—H...Se close contacts.http://scripts.iucr.org/cgi-bin/paper?S2414314616012712crystal structuretris(4-methoxyphenyl)phosphine selenide
collection DOAJ
language English
format Article
sources DOAJ
author Melina Raymundo
Clifford W. Padgett
Will E. Lynch
spellingShingle Melina Raymundo
Clifford W. Padgett
Will E. Lynch
Tris(4-methoxyphenyl)phosphine selenide
IUCrData
crystal structure
tris(4-methoxyphenyl)phosphine selenide
author_facet Melina Raymundo
Clifford W. Padgett
Will E. Lynch
author_sort Melina Raymundo
title Tris(4-methoxyphenyl)phosphine selenide
title_short Tris(4-methoxyphenyl)phosphine selenide
title_full Tris(4-methoxyphenyl)phosphine selenide
title_fullStr Tris(4-methoxyphenyl)phosphine selenide
title_full_unstemmed Tris(4-methoxyphenyl)phosphine selenide
title_sort tris(4-methoxyphenyl)phosphine selenide
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-08-01
description The title compound, C21H21O3PSe, is comprised of a P atom in a distorted tetrahedral environment, attached to the Se atom and three C atoms of the phenyl rings. The P—Se bond length is 2.1214 (12) Å. All three methoxy groups are near coplanar with their respective phenyl rings, with the angles between the phenyl ring and the C—O bond of the methoxy groups being 5.7 (2), 1.5 (4), and 5.7 (3)°. The torsion angles of the phenyl rings relative to the P=Se bond are 35.62 (10), 35.07 (13), and 44.50 (11)°. No strong intermolecular interactions were observed, but that in addition to van der Waals forces, there are C—H...π and C—H...Se close contacts.
topic crystal structure
tris(4-methoxyphenyl)phosphine selenide
url http://scripts.iucr.org/cgi-bin/paper?S2414314616012712
work_keys_str_mv AT melinaraymundo tris4methoxyphenylphosphineselenide
AT cliffordwpadgett tris4methoxyphenylphosphineselenide
AT willelynch tris4methoxyphenylphosphineselenide
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