Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl Complexes
Crystals of trans-Pt2(μ-X)2X2(CO)2 (X = Br, I) have been grown and their molecular and crystalline structures have been solved by X-ray diffraction methods. In both cases the dinuclear molecules are bent, with a bending angle of 164.6° and 156.5° for the bromide and the iodide, respectively. While t...
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| Format: | Article |
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MDPI AG
2011-07-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/16/7/6082/ |
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doaj-a3f567ece37944218cc4eccd3fa459dc2020-11-24T22:27:25ZengMDPI AGMolecules1420-30492011-07-011676082609110.3390/molecules16076082Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl ComplexesFabio MarchettiLuca LabellaDaniela Belli Dell'AmicoCrystals of trans-Pt2(μ-X)2X2(CO)2 (X = Br, I) have been grown and their molecular and crystalline structures have been solved by X-ray diffraction methods. In both cases the dinuclear molecules are bent, with a bending angle of 164.6° and 156.5° for the bromide and the iodide, respectively. While the structure of the bromo-derivative is reported here for the first time, a modification of trans-Pt2(μ-I)2I2(CO)2 with planar centrosymmetric molecules is known. This appears to be a rare case of a platinum(II) halo-bridged derivative structurally characterized in both bent and planar forms.http://www.mdpi.com/1420-3049/16/7/6082/platinumdinuclear complexeshalo-bridged complexes |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Fabio Marchetti Luca Labella Daniela Belli Dell'Amico |
| spellingShingle |
Fabio Marchetti Luca Labella Daniela Belli Dell'Amico Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl Complexes Molecules platinum dinuclear complexes halo-bridged complexes |
| author_facet |
Fabio Marchetti Luca Labella Daniela Belli Dell'Amico |
| author_sort |
Fabio Marchetti |
| title |
Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl Complexes |
| title_short |
Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl Complexes |
| title_full |
Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl Complexes |
| title_fullStr |
Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl Complexes |
| title_full_unstemmed |
Bent Dinuclear Platinum(II) Halo-Bridged Carbonyl Complexes |
| title_sort |
bent dinuclear platinum(ii) halo-bridged carbonyl complexes |
| publisher |
MDPI AG |
| series |
Molecules |
| issn |
1420-3049 |
| publishDate |
2011-07-01 |
| description |
Crystals of trans-Pt2(μ-X)2X2(CO)2 (X = Br, I) have been grown and their molecular and crystalline structures have been solved by X-ray diffraction methods. In both cases the dinuclear molecules are bent, with a bending angle of 164.6° and 156.5° for the bromide and the iodide, respectively. While the structure of the bromo-derivative is reported here for the first time, a modification of trans-Pt2(μ-I)2I2(CO)2 with planar centrosymmetric molecules is known. This appears to be a rare case of a platinum(II) halo-bridged derivative structurally characterized in both bent and planar forms. |
| topic |
platinum dinuclear complexes halo-bridged complexes |
| url |
http://www.mdpi.com/1420-3049/16/7/6082/ |
| work_keys_str_mv |
AT fabiomarchetti bentdinuclearplatinumiihalobridgedcarbonylcomplexes AT lucalabella bentdinuclearplatinumiihalobridgedcarbonylcomplexes AT danielabellidellamico bentdinuclearplatinumiihalobridgedcarbonylcomplexes |
| _version_ |
1725750087851704320 |