(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II)

(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II)

In the title compound, [RuCl2(C6H6)(C19H17P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η6-benzene) = 1.6894 (11) Å, Ru&#82...

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Bibliographic Details
Main Authors: Alfred Muller, Wade L. Davis
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812037154
Description
Summary:In the title compound, [RuCl2(C6H6)(C19H17P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η6-benzene) = 1.6894 (11) Å, Ru—P = 2.3466 (6), Ru—Cl(avg.) = 2.4127 (7) Å; Cl—Ru—Cl = 88.07 (2) and Cl—Ru—P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyldiphenylphosphane was calculated to be 143°. In the crystal C—H...Cl and C—H...π interactions are observed.
ISSN:1600-5368

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