(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II)
In the title compound, [RuCl2(C6H6)(C19H17P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η6-benzene) = 1.6894 (11) Å, Ru&#82...
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| Format: | Article |
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International Union of Crystallography
2012-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812037154 |
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doaj-a4a9492a4a3b45f49621c5bfff7c73da2020-11-24T21:32:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1232m123310.1107/S1600536812037154(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II)Alfred MullerWade L. DavisIn the title compound, [RuCl2(C6H6)(C19H17P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η6-benzene) = 1.6894 (11) Å, Ru—P = 2.3466 (6), Ru—Cl(avg.) = 2.4127 (7) Å; Cl—Ru—Cl = 88.07 (2) and Cl—Ru—P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyldiphenylphosphane was calculated to be 143°. In the crystal C—H...Cl and C—H...π interactions are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812037154 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Alfred Muller Wade L. Davis |
| spellingShingle |
Alfred Muller Wade L. Davis (η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II) Acta Crystallographica Section E |
| author_facet |
Alfred Muller Wade L. Davis |
| author_sort |
Alfred Muller |
| title |
(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II) |
| title_short |
(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II) |
| title_full |
(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II) |
| title_fullStr |
(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II) |
| title_full_unstemmed |
(η6-Benzene)(benzyldiphenylphosphane)dichloridoruthenium(II) |
| title_sort |
(η6-benzene)(benzyldiphenylphosphane)dichloridoruthenium(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-10-01 |
| description |
In the title compound, [RuCl2(C6H6)(C19H17P)], the RuII atom has a distorted pseudo-octahedral coordination environment with the metrical parameters around the metallic core as Ru—centroid(η6-benzene) = 1.6894 (11) Å, Ru—P = 2.3466 (6), Ru—Cl(avg.) = 2.4127 (7) Å; Cl—Ru—Cl = 88.07 (2) and Cl—Ru—P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyldiphenylphosphane was calculated to be 143°. In the crystal C—H...Cl and C—H...π interactions are observed. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812037154 |
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AT alfredmuller amp9516benzenebenzyldiphenylphosphanedichloridorutheniumii AT wadeldavis amp9516benzenebenzyldiphenylphosphanedichloridorutheniumii |
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