2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate
In the title compound, C27H27N7O9·CH3CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)&...
Main Author: | |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2010-12-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810047185 |
id |
doaj-a5057e61a7be4b89a5efa82fb7c9b7c4 |
---|---|
record_format |
Article |
spelling |
doaj-a5057e61a7be4b89a5efa82fb7c9b7c42020-11-25T00:54:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612o3222o322310.1107/S16005368100471852-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvateKwang HaIn the title compound, C27H27N7O9·CH3CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intramolecular O—H...N hydrogen bonds between the hydroxy O atoms and the imine N atoms, with O...N distances in the range 2.607 (3)–2.665 (3) Å, form nearly planar six-membered rings. In the crystal, weak intermolecular C—H...O and C—H...N hydrogen bonds occur and several intra- and intermolecular π–π interactions are present between adjacent benzene rings, with a shortest centroid–centroid distance of 3.507 (2) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536810047185 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kwang Ha |
spellingShingle |
Kwang Ha 2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate Acta Crystallographica Section E |
author_facet |
Kwang Ha |
author_sort |
Kwang Ha |
title |
2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_short |
2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_full |
2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_fullStr |
2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_full_unstemmed |
2-[(2-{Bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
title_sort |
2-[(2-{bis[2-(2-hydroxy-5-nitrobenzylideneamino)ethyl]amino}ethyl)iminomethyl]-4-nitrophenol acetonitrile monosolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-12-01 |
description |
In the title compound, C27H27N7O9·CH3CN, the three nitro groups of the polydentate tripodal Schiff base are located approximately parallel to their respective carrier benzene rings, making dihedral angles of 3.9 (4), 5.0 (4) and 6.3 (4)°. Intramolecular O—H...N hydrogen bonds between the hydroxy O atoms and the imine N atoms, with O...N distances in the range 2.607 (3)–2.665 (3) Å, form nearly planar six-membered rings. In the crystal, weak intermolecular C—H...O and C—H...N hydrogen bonds occur and several intra- and intermolecular π–π interactions are present between adjacent benzene rings, with a shortest centroid–centroid distance of 3.507 (2) Å. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810047185 |
work_keys_str_mv |
AT kwangha 22bis22hydroxy5nitrobenzylideneaminoethylaminoethyliminomethyl4nitrophenolacetonitrilemonosolvate |
_version_ |
1725233626007732224 |