Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization

New heterometallic aluminium-alkali metal compounds have been prepared using Schiff bases with electron withdrawing substituents as ligands. The synthesis of these new species was achieved via the reaction of AlMe<sub>3</sub> with the freshly prepared alkali-metallated ligand. The deriva...

Full description

Bibliographic Details
Main Authors:	Francisco M. García-Valle, Vanessa Tabernero, Tomás Cuenca, Jesús Cano, Marta E. G. Mosquera
Format:	Article
Language:	English
Published:	MDPI AG 2018-11-01
Series:	Molecules
Subjects:	aluminium alkali metals Schiff bases heterometallic compounds
Online Access:	https://www.mdpi.com/1420-3049/23/12/3108

id	doaj-a5288f9c559b4c1f82fc874351dcc1f2
record_format	Article
spelling	doaj-a5288f9c559b4c1f82fc874351dcc1f22020-11-24T21:39:26ZengMDPI AGMolecules1420-30492018-11-012312310810.3390/molecules23123108molecules23123108Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure StabilizationFrancisco M. García-Valle0Vanessa Tabernero1Tomás Cuenca2Jesús Cano3Marta E. G. Mosquera4Departamento de Química Orgánica y Química Inorgánica, Instituto de Investigacion en Química “Andres M. del Río” (IQAR) Universidad de Alcalá, Campus Universitario, 28871-Alcala de Henares, Madrid, SpainDepartamento de Química Orgánica y Química Inorgánica, Instituto de Investigacion en Química “Andres M. del Río” (IQAR) Universidad de Alcalá, Campus Universitario, 28871-Alcala de Henares, Madrid, SpainDepartamento de Química Orgánica y Química Inorgánica, Instituto de Investigacion en Química “Andres M. del Río” (IQAR) Universidad de Alcalá, Campus Universitario, 28871-Alcala de Henares, Madrid, SpainDepartamento de Química Orgánica y Química Inorgánica, Instituto de Investigacion en Química “Andres M. del Río” (IQAR) Universidad de Alcalá, Campus Universitario, 28871-Alcala de Henares, Madrid, SpainDepartamento de Química Orgánica y Química Inorgánica, Instituto de Investigacion en Química “Andres M. del Río” (IQAR) Universidad de Alcalá, Campus Universitario, 28871-Alcala de Henares, Madrid, SpainNew heterometallic aluminium-alkali metal compounds have been prepared using Schiff bases with electron withdrawing substituents as ligands. The synthesis of these new species was achieved via the reaction of AlMe<sub>3</sub> with the freshly prepared alkali-metallated ligand. The derivatives formed were characterized by NMR in solution and by single crystal X-ray diffraction in the solid state. Aluminate derivatives with lithium and sodium were prepared and a clear influence of the alkali metal in the final outcome is observed. The presence of a Na···F interaction in the solid state has a stabilization effect and the species [NaAlMe<sub>3</sub>L]<sub>2</sub> can de isolated for the first time, which was not possible when using Schiff bases without electron withdrawing substituents as ligands.https://www.mdpi.com/1420-3049/23/12/3108aluminiumalkali metalsSchiff basesheterometallic compounds
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Francisco M. García-Valle Vanessa Tabernero Tomás Cuenca Jesús Cano Marta E. G. Mosquera
spellingShingle	Francisco M. García-Valle Vanessa Tabernero Tomás Cuenca Jesús Cano Marta E. G. Mosquera Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization Molecules aluminium alkali metals Schiff bases heterometallic compounds
author_facet	Francisco M. García-Valle Vanessa Tabernero Tomás Cuenca Jesús Cano Marta E. G. Mosquera
author_sort	Francisco M. García-Valle
title	Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization
title_short	Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization
title_full	Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization
title_fullStr	Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization
title_full_unstemmed	Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization
title_sort	aluminates with fluorinated schiff bases: influence of the alkali metal–fluorine interactions in structure stabilization
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2018-11-01
description	New heterometallic aluminium-alkali metal compounds have been prepared using Schiff bases with electron withdrawing substituents as ligands. The synthesis of these new species was achieved via the reaction of AlMe<sub>3</sub> with the freshly prepared alkali-metallated ligand. The derivatives formed were characterized by NMR in solution and by single crystal X-ray diffraction in the solid state. Aluminate derivatives with lithium and sodium were prepared and a clear influence of the alkali metal in the final outcome is observed. The presence of a Na···F interaction in the solid state has a stabilization effect and the species [NaAlMe<sub>3</sub>L]<sub>2</sub> can de isolated for the first time, which was not possible when using Schiff bases without electron withdrawing substituents as ligands.
topic	aluminium alkali metals Schiff bases heterometallic compounds
url	https://www.mdpi.com/1420-3049/23/12/3108
work_keys_str_mv	AT franciscomgarciavalle aluminateswithfluorinatedschiffbasesinfluenceofthealkalimetalfluorineinteractionsinstructurestabilization AT vanessatabernero aluminateswithfluorinatedschiffbasesinfluenceofthealkalimetalfluorineinteractionsinstructurestabilization AT tomascuenca aluminateswithfluorinatedschiffbasesinfluenceofthealkalimetalfluorineinteractionsinstructurestabilization AT jesuscano aluminateswithfluorinatedschiffbasesinfluenceofthealkalimetalfluorineinteractionsinstructurestabilization AT martaegmosquera aluminateswithfluorinatedschiffbasesinfluenceofthealkalimetalfluorineinteractionsinstructurestabilization
_version_	1725931451477655552

Aluminates with Fluorinated Schiff Bases: Influence of the Alkali Metal–Fluorine Interactions in Structure Stabilization

Similar Items