[N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)

[N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)

In the title molecule, [V(C15H10I2N2O2)(CH3O)O(CH3OH)], the VV atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidate (L) ligand, one oxide O atom, one methanolate [V—O = 1.761 (3)&...

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Main Author: Lin Liu
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811010385
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spelling doaj-a5646ed81b714ed4a470b9370c01cd1a2020-11-24T21:50:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m482m48210.1107/S1600536811010385[N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)Lin LiuIn the title molecule, [V(C15H10I2N2O2)(CH3O)O(CH3OH)], the VV atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidate (L) ligand, one oxide O atom, one methanolate [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4) Å] O atom in a distorted octahedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)°. In the crystal, intermolecular O—H...N hydrogen bonds link pairs of molecules into centrosymmetric dimers which exhibit π–π interactions between the aromatic rings [centroid–centroid distance = 3.677 (5) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536811010385
collection DOAJ
language English
format Article
sources DOAJ
author Lin Liu
spellingShingle Lin Liu
[N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
Acta Crystallographica Section E
author_facet Lin Liu
author_sort Lin Liu
title [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
title_short [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
title_full [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
title_fullStr [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
title_full_unstemmed [N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
title_sort [n′-(3,5-diiodo-2-oxidobenzylidene-κo)-4-methylbenzohydrazidato-κ2n′,o](methanol-κo)(methanolato-κo)oxidovanadium(v)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-04-01
description In the title molecule, [V(C15H10I2N2O2)(CH3O)O(CH3OH)], the VV atom is coordinated by one N and two O atoms from an N′-(3,5-diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidate (L) ligand, one oxide O atom, one methanolate [V—O = 1.761 (3) Å] and one methanol [V—O = 2.383 (4) Å] O atom in a distorted octahedral geometry. In the L ligand, the two benzene rings are nearly parallel, forming a dihedral angle of 2.0 (1)°. In the crystal, intermolecular O—H...N hydrogen bonds link pairs of molecules into centrosymmetric dimers which exhibit π–π interactions between the aromatic rings [centroid–centroid distance = 3.677 (5) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536811010385
work_keys_str_mv AT linliu namp824235diiodo2oxidobenzylideneamp954o4methylbenzohydrazidatoamp9542namp8242omethanolamp954omethanolatoamp954ooxidovanadiumv
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