Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon Fibers
Nowadays, wastewater treatment is important for eliminating organic and inorganic contaminants. Among organic pollutants, colors have a great impact on environmental pollution. Physical adsorption by activated carbons is very useful in removing pollutants and wastewater treatment. In this study, an...
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Water and Wastewater Consulting Engineers Research Development
2020-11-01
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doaj-a574605ce16145f19850493524abea842021-04-02T18:51:55ZengWater and Wastewater Consulting Engineers Research Developmentآب و فاضلاب1024-59362383-09052020-11-0131512913910.22093/wwj.2020.191003.2890115597Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon FibersAmir Rabbi0Fatemeh Dadashian1Mansooreh Soleimani2PhD, Dept. of Textile Engineering, Amirkabir University of Technology, Tehran, IranAssoc. Prof., Dept. of Textile Engineering, Amirkabir University of Technology, Tehran, IranAssoc. Prof., Dept. of Chemical Engineering, Amirkabir University of Technology, Tehran, IranNowadays, wastewater treatment is important for eliminating organic and inorganic contaminants. Among organic pollutants, colors have a great impact on environmental pollution. Physical adsorption by activated carbons is very useful in removing pollutants and wastewater treatment. In this study, an activated carbon fiber with high mechanical properties and adsorption capacity was prepared through thermal stabilization and chemical activation of acrylic fibers. Nitrogen adsorption/desorption analysis, Fourier transform infrared spectroscopy (FTIR) and measurement of mechanical properties and iodine number were used to investigate different characteristics of the obtained adsorbent. The potential of these new adsorbents for removal of methylene blue (MB) from aqueous solution was investigated in the batch experiments and the influence of main operating parameters, including pH, and the initial dye concentration was studied. Rapid and relatively complete removal (about 95%) of MB dye was achieved at the pH of 12 and initial dye concentration of 100 mg/L. Moreover, it was revealed that the experimental data could be expressed well by the Langmuir and pseudo-second-order model, such that the maximum amount of monolayer adsorption was about 324.83 mg/g. The thermodynamic parameters indicated the spontaneous nature of the adsorption process. According to all results, the mechanical properties and adsorption capacity of the fabricated activated carbon fibers in comparison with other adsorbents exhibit relatively better properties.http://www.wwjournal.ir/article_115597_ee501c3481efc14b7950f128ff38f5fe.pdfadsorptionactivated carbon fibersmethylene blueisothermkinetics |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Amir Rabbi Fatemeh Dadashian Mansooreh Soleimani |
spellingShingle |
Amir Rabbi Fatemeh Dadashian Mansooreh Soleimani Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon Fibers آب و فاضلاب adsorption activated carbon fibers methylene blue isotherm kinetics |
author_facet |
Amir Rabbi Fatemeh Dadashian Mansooreh Soleimani |
author_sort |
Amir Rabbi |
title |
Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon Fibers |
title_short |
Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon Fibers |
title_full |
Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon Fibers |
title_fullStr |
Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon Fibers |
title_full_unstemmed |
Removal of Methylene Blue Dye Using High Performance Acrylic-Based Activated Carbon Fibers |
title_sort |
removal of methylene blue dye using high performance acrylic-based activated carbon fibers |
publisher |
Water and Wastewater Consulting Engineers Research Development |
series |
آب و فاضلاب |
issn |
1024-5936 2383-0905 |
publishDate |
2020-11-01 |
description |
Nowadays, wastewater treatment is important for eliminating organic and inorganic contaminants. Among organic pollutants, colors have a great impact on environmental pollution. Physical adsorption by activated carbons is very useful in removing pollutants and wastewater treatment. In this study, an activated carbon fiber with high mechanical properties and adsorption capacity was prepared through thermal stabilization and chemical activation of acrylic fibers. Nitrogen adsorption/desorption analysis, Fourier transform infrared spectroscopy (FTIR) and measurement of mechanical properties and iodine number were used to investigate different characteristics of the obtained adsorbent. The potential of these new adsorbents for removal of methylene blue (MB) from aqueous solution was investigated in the batch experiments and the influence of main operating parameters, including pH, and the initial dye concentration was studied. Rapid and relatively complete removal (about 95%) of MB dye was achieved at the pH of 12 and initial dye concentration of 100 mg/L. Moreover, it was revealed that the experimental data could be expressed well by the Langmuir and pseudo-second-order model, such that the maximum amount of monolayer adsorption was about 324.83 mg/g. The thermodynamic parameters indicated the spontaneous nature of the adsorption process. According to all results, the mechanical properties and adsorption capacity of the fabricated activated carbon fibers in comparison with other adsorbents exhibit relatively better properties. |
topic |
adsorption activated carbon fibers methylene blue isotherm kinetics |
url |
http://www.wwjournal.ir/article_115597_ee501c3481efc14b7950f128ff38f5fe.pdf |
work_keys_str_mv |
AT amirrabbi removalofmethylenebluedyeusinghighperformanceacrylicbasedactivatedcarbonfibers AT fatemehdadashian removalofmethylenebluedyeusinghighperformanceacrylicbasedactivatedcarbonfibers AT mansoorehsoleimani removalofmethylenebluedyeusinghighperformanceacrylicbasedactivatedcarbonfibers |
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