Synthesis of SBA-15 Type Organosilica Sorbents Using Sodium Metasilicate and Phosphonic Acid Residues
The direct template method was used for the synthesis of mesoporous organosilica sorbents of SBA-15 type with phosphonic acid groups using sodium metasilicate (SS) as a source of silica. The presence of functional groups in the synthesized samples was confirmed by IR spectroscopy and elemental analy...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Academy of Sciences of Moldova, Institute of Chemistry
2017-12-01
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| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| Subjects: | |
| Online Access: |
http://cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2017.417-Dudarko.pdf
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| Summary: | The direct template method was used for the synthesis of mesoporous organosilica sorbents of SBA-15 type with phosphonic acid groups using sodium metasilicate (SS) as a source of silica. The presence of functional groups in the synthesized samples was confirmed by IR spectroscopy and elemental analysis. This approach allowed producing relatively cheap materials with ordered structure, developed specific surface (550-700 m2/g) and high sorption volume (0.74-0.81 cm3/g). The optimal sodium metasilicate (SS):diphosphoethyltriethoxysilane (DPTS) ratio for the synthesis of SBA-15 type organosilicas with phosphonic acid residues was found to be 10:2. |
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| ISSN: | 1857-1727 2345-1688 |