Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus

The title compound, C20H22N2O2, an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar molecules in the unit cell. The molecules are linked into pairs by two N—H...O=C hydrogen bonds. The absolute configuration was confirmed by anomalous disp...

Full description

Bibliographic Details
Main Authors: Mahdi Yahyazadeh, Gerold Jerz, Dirk Selmar, Peter Winterhalter, Peter G. Jones
Format: Article
Language:English
Published: International Union of Crystallography 2017-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017014529
id doaj-a63e8871ee5949dc81cad59b1ae49b13
record_format Article
spelling doaj-a63e8871ee5949dc81cad59b1ae49b132020-11-25T00:31:09ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-11-0173111658166110.1107/S2056989017014529dx2001Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseusMahdi Yahyazadeh0Gerold Jerz1Dirk Selmar2Peter Winterhalter3Peter G. Jones4Institut für Pflanzenbiologie, Technische Universität Braunschweig, Mendelssohnstrasse 4, 38106 Braunschweig, GermanyInstitut für Lebensmittelchemie, Technische Universität Braunschweig, Schleinitzstrasse 20, 38106 Braunschweig, GermanyInstitut für Pflanzenbiologie, Technische Universität Braunschweig, Mendelssohnstrasse 4, 38106 Braunschweig, GermanyInstitut für Lebensmittelchemie, Technische Universität Braunschweig, Schleinitzstrasse 20, 38106 Braunschweig, GermanyInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, GermanyThe title compound, C20H22N2O2, an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar molecules in the unit cell. The molecules are linked into pairs by two N—H...O=C hydrogen bonds. The absolute configuration was confirmed by anomalous dispersion effects as S at the 3 and 15 positions, and R at the 7 position.http://scripts.iucr.org/cgi-bin/paper?S2056989017014529crystal structureindole alkaloidabsolute configuration
collection DOAJ
language English
format Article
sources DOAJ
author Mahdi Yahyazadeh
Gerold Jerz
Dirk Selmar
Peter Winterhalter
Peter G. Jones
spellingShingle Mahdi Yahyazadeh
Gerold Jerz
Dirk Selmar
Peter Winterhalter
Peter G. Jones
Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
indole alkaloid
absolute configuration
author_facet Mahdi Yahyazadeh
Gerold Jerz
Dirk Selmar
Peter Winterhalter
Peter G. Jones
author_sort Mahdi Yahyazadeh
title Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus
title_short Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus
title_full Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus
title_fullStr Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus
title_full_unstemmed Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus
title_sort crystal structure of akuammicine, an indole alkaloid from catharanthus roseus
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2017-11-01
description The title compound, C20H22N2O2, an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar molecules in the unit cell. The molecules are linked into pairs by two N—H...O=C hydrogen bonds. The absolute configuration was confirmed by anomalous dispersion effects as S at the 3 and 15 positions, and R at the 7 position.
topic crystal structure
indole alkaloid
absolute configuration
url http://scripts.iucr.org/cgi-bin/paper?S2056989017014529
work_keys_str_mv AT mahdiyahyazadeh crystalstructureofakuammicineanindolealkaloidfromcatharanthusroseus
AT geroldjerz crystalstructureofakuammicineanindolealkaloidfromcatharanthusroseus
AT dirkselmar crystalstructureofakuammicineanindolealkaloidfromcatharanthusroseus
AT peterwinterhalter crystalstructureofakuammicineanindolealkaloidfromcatharanthusroseus
AT petergjones crystalstructureofakuammicineanindolealkaloidfromcatharanthusroseus
_version_ 1725323330500689920