Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus
The title compound, C20H22N2O2, an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar molecules in the unit cell. The molecules are linked into pairs by two N—H...O=C hydrogen bonds. The absolute configuration was confirmed by anomalous disp...
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doaj-a63e8871ee5949dc81cad59b1ae49b132020-11-25T00:31:09ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-11-0173111658166110.1107/S2056989017014529dx2001Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseusMahdi Yahyazadeh0Gerold Jerz1Dirk Selmar2Peter Winterhalter3Peter G. Jones4Institut für Pflanzenbiologie, Technische Universität Braunschweig, Mendelssohnstrasse 4, 38106 Braunschweig, GermanyInstitut für Lebensmittelchemie, Technische Universität Braunschweig, Schleinitzstrasse 20, 38106 Braunschweig, GermanyInstitut für Pflanzenbiologie, Technische Universität Braunschweig, Mendelssohnstrasse 4, 38106 Braunschweig, GermanyInstitut für Lebensmittelchemie, Technische Universität Braunschweig, Schleinitzstrasse 20, 38106 Braunschweig, GermanyInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, GermanyThe title compound, C20H22N2O2, an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar molecules in the unit cell. The molecules are linked into pairs by two N—H...O=C hydrogen bonds. The absolute configuration was confirmed by anomalous dispersion effects as S at the 3 and 15 positions, and R at the 7 position.http://scripts.iucr.org/cgi-bin/paper?S2056989017014529crystal structureindole alkaloidabsolute configuration |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mahdi Yahyazadeh Gerold Jerz Dirk Selmar Peter Winterhalter Peter G. Jones |
spellingShingle |
Mahdi Yahyazadeh Gerold Jerz Dirk Selmar Peter Winterhalter Peter G. Jones Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus Acta Crystallographica Section E: Crystallographic Communications crystal structure indole alkaloid absolute configuration |
author_facet |
Mahdi Yahyazadeh Gerold Jerz Dirk Selmar Peter Winterhalter Peter G. Jones |
author_sort |
Mahdi Yahyazadeh |
title |
Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus |
title_short |
Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus |
title_full |
Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus |
title_fullStr |
Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus |
title_full_unstemmed |
Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus |
title_sort |
crystal structure of akuammicine, an indole alkaloid from catharanthus roseus |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2017-11-01 |
description |
The title compound, C20H22N2O2, an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar molecules in the unit cell. The molecules are linked into pairs by two N—H...O=C hydrogen bonds. The absolute configuration was confirmed by anomalous dispersion effects as S at the 3 and 15 positions, and R at the 7 position. |
topic |
crystal structure indole alkaloid absolute configuration |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989017014529 |
work_keys_str_mv |
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