Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
This study is about the synthesis of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide (C16H17Cl2N3OS) compound. Single crystals of the compound were obtained by slow evaporation of N,N′-bis(4-chlorophenyl)thiourea (C13H10Cl2N2S) in N,N-dimethylformamide (C3H7NO; DMF) through recrystallization...
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De Gruyter
2021-05-01
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| Series: | Open Chemistry |
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| Online Access: | https://doi.org/10.1515/chem-2020-0061 |
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doaj-a804d8820b08454fbe23b7ff16d022a82021-10-03T07:42:27ZengDe GruyterOpen Chemistry2391-54202021-05-0119151151710.1515/chem-2020-0061Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamideOdularu Ayodele T.0Ajibade Peter A.1Oyedeji Opeoluwa O.2Mbese Johannes Z.3Puschmann Horst4Department of Chemistry, University of Fort Hare, Private Bag X1314, Alice 5700, South AfricaDepartment of Chemistry, School of Chemistry and Physics, University of KwaZulu-Natal, Pietermaritzburg Campus, Scottsville 3209, South AfricaDepartment of Chemistry, University of Fort Hare, Private Bag X1314, Alice 5700, South AfricaDepartment of Chemistry, University of Fort Hare, Private Bag X1314, Alice 5700, South AfricaChemistry Department, Durham University, Dublin, United KingdomThis study is about the synthesis of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide (C16H17Cl2N3OS) compound. Single crystals of the compound were obtained by slow evaporation of N,N′-bis(4-chlorophenyl)thiourea (C13H10Cl2N2S) in N,N-dimethylformamide (C3H7NO; DMF) through recrystallization under mild condition. Important classical N–H⋯O links the two molecules together. Results revealed that C16H17Cl2N3OS crystallized in the monoclinic space group P21/c with the respective cell parameters of a = 92,360 (4) Å, b = 7.2232 (3) Å, 25.2555 (11) Å, β = 91.376 (3), α = γ = 90°, V = 1684.40 (12) Å3, T = 119.94 (13) K and Z = 4 and Z′ = 1.https://doi.org/10.1515/chem-2020-0061thioureadimethylformamidecrystal structuremonoclinic |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Odularu Ayodele T. Ajibade Peter A. Oyedeji Opeoluwa O. Mbese Johannes Z. Puschmann Horst |
| spellingShingle |
Odularu Ayodele T. Ajibade Peter A. Oyedeji Opeoluwa O. Mbese Johannes Z. Puschmann Horst Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide Open Chemistry thiourea dimethylformamide crystal structure monoclinic |
| author_facet |
Odularu Ayodele T. Ajibade Peter A. Oyedeji Opeoluwa O. Mbese Johannes Z. Puschmann Horst |
| author_sort |
Odularu Ayodele T. |
| title |
Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide |
| title_short |
Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide |
| title_full |
Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide |
| title_fullStr |
Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide |
| title_full_unstemmed |
Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide |
| title_sort |
synthesis and crystal structure of n,n′-bis(4-chlorophenyl)thiourea n,n-dimethylformamide |
| publisher |
De Gruyter |
| series |
Open Chemistry |
| issn |
2391-5420 |
| publishDate |
2021-05-01 |
| description |
This study is about the synthesis of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide (C16H17Cl2N3OS) compound. Single crystals of the compound were obtained by slow evaporation of N,N′-bis(4-chlorophenyl)thiourea (C13H10Cl2N2S) in N,N-dimethylformamide (C3H7NO; DMF) through recrystallization under mild condition. Important classical N–H⋯O links the two molecules together. Results revealed that C16H17Cl2N3OS crystallized in the monoclinic space group P21/c with the respective cell parameters of a = 92,360 (4) Å, b = 7.2232 (3) Å, 25.2555 (11) Å, β = 91.376 (3), α = γ = 90°, V = 1684.40 (12) Å3, T = 119.94 (13) K and Z = 4 and Z′ = 1. |
| topic |
thiourea dimethylformamide crystal structure monoclinic |
| url |
https://doi.org/10.1515/chem-2020-0061 |
| work_keys_str_mv |
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